104353
Tetrafluoro-1,4-benzoquinone
97%
Synonym(s):
2,3,5,6-Tetrafluoroquinone, Fluoranil, Tetrafluorobenzoquinone
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£49.80
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£108.00
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1 G
£49.80
5 G
£108.00
About This Item
Linear Formula:
C6F4(=O)2
CAS Number:
Molecular Weight:
180.06
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
form:
solid
Assay:
97%
Recommended Products
Quality Level
Assay
97%
form
solid
mp
183-186 °C (subl.) (lit.)
functional group
fluoro
ketone
SMILES string
FC1=C(F)C(=O)C(F)=C(F)C1=O
InChI
1S/C6F4O2/c7-1-2(8)6(12)4(10)3(9)5(1)11
InChI key
JKLYZOGJWVAIQS-UHFFFAOYSA-N
General description
Tetrafluoro-1,4-benzoquinone is a fluorinated building block, commonly used as a precursor for fluoro derivatives.[1]
Application
Tetrafluoro-1,4-benzoquinone (fluoranil) can be used to prepare:
- Symmetrical or unsymmetrical ethers by coupling of two alcohols via the oxidation-reduction condensation reaction.[2]
- Azocino[4,3-b]indole scaffold, which is used as an inetermediate to prepare (±)-dasycarpidone.[3]
- Chiral and racemic charge-transfer (CT) complexes with binaphthol.[4]
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A convenient method for the preparation of symmetrical or unsymmetrical ethers by the coupling of two alcohols via a new type of oxidation-reduction condensation using tetrafluoro-1, 4-benzoquinone.
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A Facile and Convenient Synthesis of (?)-Dasycarpidone
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Generation and spectroscopic characterization of the 2, 3, 5, 6-tetramethoxy-1, 4-benzosemiquinone reactive intermediate.
Mattar SM, et al.
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Proceedings of the National Academy of Sciences of the United States of America, 104(45), 17575-17578 (2007-10-31)
We have shown previously that hydroxyl radicals (HO*) can be produced by H2O2 and halogenated quinones, independent of transition metal ions; however, the underlying molecular mechanism is still unclear. In the present study, using the electron spin resonance secondary radical
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