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115746

Sigma-Aldrich

2,2,6,6-Tetramethyl-4-piperidinol

98%

Synonym(s):

4-Hydroxy-2,2,6,6-tetramethylpiperidine

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About This Item

Empirical Formula (Hill Notation):
C9H19NO
CAS Number:
2403-88-5
Molecular Weight:
157.25
Beilstein:
105039
EC Number:
219-291-2
MDL number:
MFCD00005983
UNSPSC Code:
12352100
PubChem Substance ID:
24847236
NACRES:
NA.22
Pricing and availability is not currently available.

Assay

98%

bp

212-215 °C (lit.)

mp

129-131 °C (lit.)

functional group

hydroxyl

SMILES string

CC1(C)CC(O)CC(C)(C)N1

InChI

1S/C9H19NO/c1-8(2)5-7(11)6-9(3,4)10-8/h7,10-11H,5-6H2,1-4H3

InChI key

VDVUCLWJZJHFAV-UHFFFAOYSA-N

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Application

2,2,6,6-Tetramethyl-4-piperidinol has been used to study the green and efficient method for chemoselective deoxidization of graphene oxide via the ultraviolet irradiation[1].
2,2,6,6-tetramethyl-4-piperidinol has been used to study the irradiation of Camptothecin (CPT) in aerated dimethylsulfoxide (DMSO) solution that leads to formation of singlet oxygen[2].
Used as:
  • An additive for polymer modified hindered amine light stabilizers
  • A light stabilizer for polyamide 66 fibers containing acid blue dyes

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H314,H317

Hazard Classifications

Skin Corr. 1B - Skin Sens. 1

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
17931AIV
STBD0879V
STBC9746V
STBC8182V
STBC6691V

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Hirohisa Sato et al.
The Journal of toxicological sciences, 41(6), 793-799 (2016-11-18)
The present study aimed to evaluate the acute locally injurious property of our most current hydroxyl radical generation system by hydrogen peroxide (H2O2) photolysis. This system, which releases 3% H2O2 with a 405-nm laser, was developed in our laboratory for
Keisuke Nakamura et al.
PloS one, 8(3), e60053-e60053 (2013-03-26)
In the present study, the bactericidal effect of photo-irradiated proanthocyanidin was evaluated in relation to reactive oxygen species formation. Staphylococcus aureus suspended in proanthocyanidin aqueous solution was irradiated with light from a laser at 405 nm. The bactericidal effect of
Fei Zhao et al.
ACS nano, 6(4), 3027-3033 (2012-03-17)
We report a green and efficient method for chemoselective deoxidization of graphene oxide via the ultraviolet irradiation catalyzed with 2,2,6,6-tetramethyl-4-piperidinol. While the sp(2)-hybridized oxygen functional groups are removed after the reduction, the epoxy and hydroxyl groups are retained in the
Shunichi Shishido et al.
Scientific reports, 8(1), 12888-12888 (2018-08-29)
In the present study, we evaluated the prooxidative mode of action of photoirradiated (+)-catechin at 400 nm in relation to reactive oxygen species generation and its possible application to disinfection. Photoirradiation of (+)-catechin at a concentration of 1 mg/mL yielded not only
S X Liu et al.
Proceedings of the National Academy of Sciences of the United States of America, 98(4), 1643-1648 (2001-02-15)
Although arsenic is a well-established human carcinogen, the mechanisms by which it induces cancer remain poorly understood. We previously showed arsenite to be a potent mutagen in human-hamster hybrid (A(L)) cells, and that it induces predominantly multilocus deletions. We show
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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