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For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
92360
Chlorotrimethylsilane
puriss., ≥99.0% (GC)
Synonyme(s) :
TMCS, Trimethylchlorosilane, Trimethylsilyl chloride
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About This Item
Produits recommandés
Densité de vapeur
3.7 (vs air)
Niveau de qualité
Pression de vapeur
100 mmHg ( 25 °C)
Qualité
puriss.
Essai
≥99.0% (GC)
Forme
liquid
Température d'inflammation spontanée
752 °F
Limite d'explosivité
6.4 %
Indice de réfraction
n20/D 1.387 (lit.)
pb
57 °C (lit.)
Pf
−40 °C (lit.)
Densité
0.856 g/mL at 25 °C (lit.)
Chaîne SMILES
[H][C@@]12CC(C)(C)CC[C@]1(C)CC[C@]3(C)C2=CC[C@]4([H])[C@@]5(C)CC[C@H](O)C(C)(C)[C@]5([H])CC[C@@]34C
C[Si](C)(C)Cl
InChI
1S/C3H9ClSi/c1-5(2,3)4/h1-3H3
Clé InChI
IJOOHPMOJXWVHK-UHFFFAOYSA-N
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Description générale
Application
- Chlorotrimethylsilane can be a non-toxic alternative to mercuric chloride as activator in samarium-promoted cyclopropanation of both allylic and α-allenic alcohols.[2]
- It can be used in combination with hexamethyldisilazane for the protection of alcohols by forming trimethylsilyl ethers via silylation.[3]
- It is employed in chloromethylation of polysulfones (PSUs).[4]
- It activates lithium hydride to convert it into a hydride source for the reductive silylation of carbonyl compounds.[5]
- Chlorotrimethylsilane/lithium bromide forms an effective reagent for the conversion of alcohols to bromides.[6]
- Chlorotrimethylsilane/sodium iodide in acetonitrile is a better alternative to iodotrimethylsilane for the cleavage of esters, lactones, carbamates, and ethers. It can also be used for the conversion of alcohols to iodides.[7]
- Chlorotrimethylsilane along with silver or ammonium nitrate forms an efficient regioselective nitrating reagent for the ipso-nitration of arylboronic acids to form the corresponding nitroarenes.[8]
- Chlorotrimethylsilane along with sodium nitrite or nitrate can be used for deoximation reactions.[9]
Mention d'avertissement
Danger
Mentions de danger
Classification des risques
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A
Risques supp
Code de la classe de stockage
3 - Flammable liquids
Classe de danger pour l'eau (WGK)
WGK 1
Point d'éclair (°F)
-18.4 °F - closed cup
Point d'éclair (°C)
-28 °C - closed cup
Équipement de protection individuelle
Faceshields, Gloves, Goggles
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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