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Fenoxaprop

PESTANAL®, analytical standard

Synonyme(s) :

2-{4-[(6-Chlorobenzoxazol-2-yl)oxy]phenoxy}propionic acid

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About This Item

Formule empirique (notation de Hill):
C16H12ClNO5
Numéro CAS:
Poids moléculaire :
333.72
Beilstein:
8395406
Numéro MDL:
Code UNSPSC :
41116107
ID de substance PubChem :
Nomenclature NACRES :
NA.24
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Qualité

analytical standard

Niveau de qualité

Gamme de produits

PESTANAL®

Durée de conservation

limited shelf life, expiry date on the label

Technique(s)

HPLC: suitable
gas chromatography (GC): suitable

Application(s)

agriculture
environmental

Format

neat

Température de stockage

2-8°C

Chaîne SMILES 

CC(Oc1ccc(Oc2nc3ccc(Cl)cc3o2)cc1)C(O)=O

InChI

1S/C16H12ClNO5/c1-9(15(19)20)21-11-3-5-12(6-4-11)22-16-18-13-7-2-10(17)8-14(13)23-16/h2-9H,1H3,(H,19,20)

Clé InChI

MPPOHAUSNPTFAJ-UHFFFAOYSA-N

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Description générale

Fenoxaprop is the chiral metabolite formed due to the degradation of its parent compound – Fenoxaprop-ethyl, in soil. Fenoxaprop belongs to the group of aryloxyphenoxypropionate (APP) herbicides and has been used widely for the selective postemergence control of annual and perennial grass weeds in broadleaf crops. This systemic herbicide is primarily absorbed by leaves, translocated both acropetally and basipetally in the phloem and xylem to roots or rhizomes. Fenoxaprop acts by inhibiting acetyl CoA carboxylase (ACCase) – a key enzyme in lipid biosynthesis and blocks the production of phospholipids used in building new membranes.

According to Commission Regulation (1107/2009), fenoxaprop is not approved for use as a plant protection product in the European Union. However, a default MRL of 0.01 mg/kg is set according to Art 18(1)(b) Reg 396 / 2005.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support. The analytical standard (Pestanal) can be used to:

  • Develop an HPLC method for the determination of fenoxaprop-ethyl and fenoxaprop residues in four soil types using two extraction procedures
  • Validate the resistance of fenoxaprop in wild oats in Turkey and investigate cross and multiple resistance patterns of fenoxaprop-resistant wild oat populations
  • Investigate the degradation of fenoxaprop-ethyl and fenoxaprop in three soils were under native and sterilized conditions using enantioselective high-performance liquid chromatography (HPLC)
  • Determine the effect of soil moisture, temperature, and light intensity on the spray deposition of fenoxaprop and imazamethabenz applied to wild oat plants
  • Investigate and quantify the resistance of Japanese foxtail (Alopecurus japonicus) to fenoxaprop and pinoxaden in China and elucidate the basis of resistance to these herbicides

Informations légales

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

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Environment

Mention d'avertissement

Warning

Mentions de danger

Conseils de prudence

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Équipement de protection individuelle

Eyeshields, Gloves, type N95 (US)


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Certificats d'analyse (COA)

Lot/Batch Number

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Susana Meseguer-Lloret et al.
Applied spectroscopy, 70(2), 312-321 (2016-02-24)
Two new chemiluminescence (CL) methods are described for the determination of the herbicide 4-(4-chloro-o-tolyloxy) butyric acid (MCPB). First, a flow injection chemiluminescence (FI-CL) method is proposed. In this method, MCPB is photodegraded with an ultraviolet (UV) lamp and the photoproducts
Shizuka Saito-Shida et al.
Analytical methods : advancing methods and applications, 13(7), 894-902 (2021-01-26)
A reliable multiresidue method was developed for determining multiclass acidic pesticides in cereal grains, legumes, vegetables, and fruits. The target pesticides comprise 75 compounds, including phenoxy acid, sulfonylurea, imidazoline, and triazolopyrimidine herbicides, with acidic dissociation constant (pKa) values of 1.9-5.9.
Mahboob Nemati et al.
Journal of separation science, 43(6), 1119-1127 (2019-12-27)
A stir bar sorptive extraction method coupled with deep eutectic solvent based solidification of floating organic droplets-dispersive liquid-liquid microextraction has been used for the simultaneous derivatization and extraction of some acidic pesticides in tomato samples. In this method, initially the
Giovanni D'Orazio et al.
Journal of chromatography. A, 1623, 461213-461213 (2020-06-09)
In the present study separation of enantiomers of some chiral neutral, basic and weakly acidic analytes was investigated on the chiral stationary phase (CSP) made by covalent immobilization of amylose tris(3-chloro-5-methylphenylcarbamate) onto aminopropylsilanized (APS) silica in nano-liquid chromatography (nano-LC) in
Giovanni D'Orazio et al.
Journal of chromatography. A, 1606, 460425-460425 (2019-09-01)
In the present study separation of enantiomers of some chiral neutral and weakly acidic analytes was investigated on the chiral stationary phase (CSP) made by covalent immobilization of amylose tris(3-chloro-5-methylphenylcarbamate) onto silica in nano-liquid chromatography (nano-LC) and capillary electrochromatography (CEC)

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