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14520

Sigma-Aldrich

Tin(IV) chloride

fuming, ≥99%

Synonyme(s) :

Stannic chloride

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About This Item

Formule linéaire :
SnCl4
Numéro CAS:
7646-78-8
Poids moléculaire :
260.52
Numéro CE :
231-588-9
Numéro MDL:
MFCD00011242
Code UNSPSC :
12352100
ID de substance PubChem :
329750518

Niveau de qualité

100

Pureté

≥99%

Pertinence de la réaction

reagent type: catalyst
core: tin

Densité

2.217 g/mL at 20 °C (lit.)

Traces d'anions

sulfate (SO42-): ≤100 mg/kg

Traces de cations

As: ≤50 mg/kg
Fe: ≤10 mg/kg

Chaîne SMILES 

Cl[Sn](Cl)(Cl)Cl

InChI

1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4

Clé InChI

HPGGPRDJHPYFRM-UHFFFAOYSA-J

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Pictogrammes

CorrosionExclamation mark
GHS05,GHS07

Mention d'avertissement

Danger

Mentions de danger

H314,H335,H412

Classification des risques

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificats d'analyse (COA)

Lot/Batch Number
1417530
80250
60320
20720
11230

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Consulter la Bibliothèque de documents

Yasuyuki Kita et al.
The Journal of organic chemistry, 71(14), 5191-5197 (2006-07-01)
The Lewis acid-promoted rearrangement of 2,2,3,3-tetrasubstituted 2,3-epoxy alcohols with several kinds of protecting groups was investigated. When SnCl4 is used as a Lewis acid, the reaction proceeds in a regio- and stereo-controlled manner to afford two types of carbonyl compounds
Gerry A Griffith et al.
Journal of the American Chemical Society, 128(40), 13130-13141 (2006-10-05)
Difluorinated alkenoate ethyl 3,3-difluoro-2-(N,N-diethylcarbamoyloxy)-2-propenoate reacts rapidly and in high yield with furan and a range of substituted furans in the presence of a tin(IV) catalyst. Non-fluorinated congener 2-(N,N-diethylcarbamoyloxy)-2-propenoate fails to react at all under the same conditions. These reactions have
Raquel Coronel et al.
Molecular neurobiology, 56(2), 1248-1261 (2018-06-09)
Amyloid precursor protein (APP) is implicated in neural development as well as in the pathology of Alzheimer's disease (AD); however, its biological function still remains unclear. It has been reported that APP stimulates the proliferation and neuronal differentiation of neural
Gary B Evans et al.
The Journal of organic chemistry, 69(6), 2217-2220 (2004-04-03)
Promotion by Lewis acid of the addition of some aryllithiums to a carbohydrate-based imine, which has allowed a more facile synthesis of some imino-C-nucleoside analogues, is described. Use of the corresponding nitrone does not assist in some cases, but lithiated
Colin O'Brien et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(3), 902-909 (2006-11-07)
The reaction of silylated nucleophiles with 6,1-anhydroglucopyranuronic acid (glucuronic acid 6,1-lactones) catalysed by tin(IV) chloride provides 1,2-trans or 1,2-cis (deoxy)glycosides in a manner dependent on the donor structure. The alpha-glycoside was obtained for reactions of the donor with the 2-acyl
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