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M11103

Sigma-Aldrich

4-Methoxybenzylamine

98%

Synonyme(s) :

(4-Methoxyphenyl)methanamine, (p-Methoxyphenyl)methanamine, 1-Aminomethyl-4-methoxybenzene, 4-Methoxybenzenemethanamine, Anisylamine, p-Methoxybenzylamine

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About This Item

Formule linéaire :
CH3OC6H4CH2NH2
Numéro CAS:
2393-23-9
Poids moléculaire :
137.18
Beilstein:
508206
Numéro CE :
219-247-2
Numéro MDL:
MFCD00008122
Code UNSPSC :
12352100
ID de substance PubChem :
24896615
Nomenclature NACRES :
NA.22
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Niveau de qualité

200

Essai

98%

Forme

liquid

Indice de réfraction

n20/D 1.546 (lit.)

pb

236-237 °C (lit.)

Densité

1.05 g/mL at 25 °C (lit.)

Chaîne SMILES 

COc1ccc(CN)cc1

InChI

1S/C8H11NO/c1-10-8-4-2-7(6-9)3-5-8/h2-5H,6,9H2,1H3

Clé InChI

IDPURXSQCKYKIJ-UHFFFAOYSA-N

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Catégories apparentées

Application

4-Methoxybenzylamine is a primary amine and can be used for:
  • Amination reaction of functionalized aryl bromides.[1]
  • Synthesis of functionalized organopolyphosphazenes for in vivo applications.[2]
  • Synthesis of analogs of myoseverin, 8-azapurine, for their antiproliferative activities.[3]
  • Studying the deprotection procedures of amino protecting groups such as 2-nitro- and 2,4-dinitrobenzenesulfonamides.[4]

Pictogrammes

Corrosion
GHS05

Mention d'avertissement

Danger

Mentions de danger

H314

Classification des risques

Eye Dam. 1 - Skin Corr. 1B

Code de la classe de stockage

8A - Combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Équipement de protection individuelle

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificats d'analyse (COA)

Lot/Batch Number
0000146677
STBK1104
0000094026
STBJ4737
0000077892

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Consulter la Bibliothèque de documents

Synthesis and biological activity of 8-azapurine and pyrazolo [4, 3-d] pyrimidine analogues of myoseverin.
Krystof V, et al.
European Journal of Medicinal Chemistry, 41(12), 1405-1411 (2006)
Anna Berlicka et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 9(10), 1359-1366 (2010-09-08)
A variety of primary and secondary benzylic amines were oxidized efficiently to N-benzylidenebenzylamines and imines, respectively, using 2,7,12,17-tetrapropylporphycene (H(2)TPrPc) photocatalyst and blue light emitting diodes (LEDs). The photooxidation of 4-methoxybenzylamine in the presence of H(2)TPrPc and its tin(IV) complex Sn(TPrPc)Cl(2)
Synthesis and characterization of novel polyorganophosphazenes substituted with 4-methoxybenzylamine and 4-methoxyphenethylamine for in vitro release of indomethacin and 5-fluorouracil.
Gudasi KB, et al.
Reactive and Functional Polymers, 66(10), 1149-1157 (2006)
T Jonsson et al.
Biochemistry, 33(49), 14871-14878 (1994-12-13)
Competitive kH/kT and kD/kT kinetic isotope effects on p-methoxybenzylamine oxidation by the 8 alpha-S-cysteinyl flavin adenine dinucleotide (FAD)-dependent enzyme monoamine oxidase B (MAO-B) have been measured as a function of temperature. At pH 7.5, exponents relating observed kH/kT and kD/kT
Mild and efficient copper-catalyzed amination of aryl bromides with primary alkylamines.
Kwong FY and Buchwald SL
Organic Letters, 5(6), 793-796 (2003)
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Questions

1–2 sur 2 questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 réponse

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 réponse

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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