938726

ImPy-Dipop-Dipp

• Synonyme(s) : 5-(2,6-diisopropoxyphenyl)-2-(2,6-diisopropylphenyl)imidazo[1,5-a]pyridin-2-ium chloride
• Formule empirique (notation de Hill): C₃₁H₃₉ClN₂O₂
• Numéro CAS: 2983007-49-2
• Poids moléculaire : 507.11
• Code UNSPSC : 12352100

Propriétés

• Forme: powder
• Niveau de qualité: 100
• Capacité de réaction: reaction type: Cross Couplings
• Couleur: white
• Chaîne SMILES: CC(C1=CC=CC(C(C)C)=C1[N+]2=CN3C(C4=C(OC(C)C)C=CC=C4OC(C)C)=CC=CC3=C2)C.[Cl-]
• InChI: 1S/C31H39N2O2.ClH/c1-20(2)25-13-10-14-26(21(3)4)31(25)32-18-24-12-9-15-27(33(24)19-32)30-28(34-22(5)6)16-11-17-29(30)35-23(7)8;/h9-23H,1-8H3;1H/q+1;/p-1
• Clé InChI: XMDMIAJKGFBECK-UHFFFAOYSA-M

Description

Description générale

ImPy-Dipop-Dipp is an NHC precursor developed in the Szostak group. The ligand is useful in a range of catalytic transformations, and is particulary well suited to the following: Suzuki-Miyaura cross-coupling of aryl mesylates and tosylates, Suzuki–Miyaura cross-coupling of nitroarenes (Ar–NO₂), Buchwald-Hartwig amination of alkyl sulfoxides

Application

Suzuki-Miyaura cross-coupling of aryl mesylates and tosylates Suzuki–Miyaura cross-coupling of nitroarenes (Ar–NO₂) or aryl sulfamates Buchwald-Hartwig amination of alkyl sulfoxides or aryl sulfamates

Caractéristiques et avantages

ImPy-Dipop-Dipp is an asymmetric NHC ligand precursor. It forms air-and moisture stable complexes with transition metals and is particulary effective in palladium catalyzed cross-coupling reactions.

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable