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806781

Sigma-Aldrich

TPBi

Synonyme(s) :

2,2′,2"-(1,3,5-Benzinetriyl)-tris(1-phenyl-1-H-benzimidazole)

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500 MG
555,00 €

555,00 €


Disponible pour expédition le17 avril 2025Détails


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500 MG
555,00 €

About This Item

Formule empirique (notation de Hill) :
C45H30N6
Numéro CAS:
Poids moléculaire :
654.76
Numéro MDL:
Code UNSPSC :
12352103
ID de substance PubChem :
Nomenclature NACRES :
NA.23

555,00 €


Disponible pour expédition le17 avril 2025Détails


Devis pour commande en gros

Essai

≥99.5% (HPLC)

Niveau de qualité

Forme

powder

Pf

272-277 °C

Énergie orbitale

HOMO 6.2 eV 
LUMO 2.7 eV 

Performance des dispositifs OLED

ITO/MoO3/NPB/Cz-BTPE/TPBi/LiF/Al (ref 2)

  • Color: blue
  • Max. Luminance: 9911 Cd/m2
  • Max. EQE: 1.9 %
  • Turn-On Voltage: 4.9 V

ITO/MoO3/NPB/Ph-BTPE/TPBi/LiF/Al
  • Color: blue
  • Max. Luminance: 6497 Cd/m2
  • Max. EQE: 1.9 %
  • Turn-On Voltage: 5.3 V

ITO/MoO3/NPB/isopro-BTPE/TPBi/LiF/Al(ref 2)
  • Color: blue
  • Max. Luminance: 1127 Cd/m2
  • Max. EQE: 1.7 %
  • Turn-On Voltage: 5.3 V

ITO/MoO3/NPB/methyl-BTPE/TPBi/LiF/Al (ref 2)
  • Color: blue
  • Max. Luminance: 1976 Cd/m2
  • Max. EQE: 1.3 %
  • Turn-On Voltage: 5.3 V

Chaîne SMILES 

C1(C2=NC(C=CC=C3)=C3N2C4=CC=CC=C4)=CC(C5=NC(C=CC=C6)=C6N5C7=CC=CC=C7)=CC(C8=NC(C=CC=C9)=C9N8C%10=CC=CC=C%10)=C1

InChI

1S/C45H30N6/c1-4-16-34(17-5-1)49-40-25-13-10-22-37(40)46-43(49)31-28-32(44-47-38-23-11-14-26-41(38)50(44)35-18-6-2-7-19-35)30-33(29-31)45-48-39-24-12-15-27-42(39)51(45)36-20-8-3-9-21-36/h1-30H

Clé InChI

GEQBRULPNIVQPP-UHFFFAOYSA-N

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Description générale

TPBi is an organic semiconductor that displays high electron mobility (3.3×10−5 cm2 V−1 s−1) and high glass transition temperature. It is widely used as an electron transport layer(ETL) in QLEDs and OLEDs, which is a cathode buffer layer in organic solar cells.[1]

The increase in power conversion efficiency of the device on the addition of TBPi is attributed to the following reasons:
  • Preventing exciton from quenching at the acceptor/cathode interface.
  • Acting as an optical spacer.
  • Forming a passivating layer.[2]

Application

TPBi can be used to fabricate an electron transport layer for organic-inorganic hybrid perovskite LEDs.[3]

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Certificats d'analyse (COA)

Lot/Batch Number

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Les clients ont également consulté

Study on Electron Transport Characterization in TPBi Thin Films and OLED Application
Yanping Wang, et al.
The Journal of Physical Chemistry C, 125, 16753-16758 (2021)
Organic photovoltaic cells based on TPBi as a cathode buffer layer
Junsheng Yu, et al.
Solar Energy Materials and Solar Cells, 95, 664-668 (2011)
Semi-transparent organic-inorganic hybrid perovskite light-emitting diodes fabricated under high relative humidity
Taejun Kim, et al.
Solid-state electronics, 165, 107749-107749 (2020)
Efficient blue organic light-emitting diodes employing thermally activated delayed fluorescence
Qisheng Z, et al.
Nature Photonics, 8, 326-332 (2014)
Largely blue-shifted emission through minor structural modifications: molecular design, synthesis, aggregation-induced emission and deep-blue OLED application
Jing H, et al.
Chemical Communications (Cambridge, England), 50, 2136-2138 (2014)

Articles

Organic Light-emitting Diodes (OLEDs) are solid-state devices that transform electrical energy into light. OLEDs are considered the next generation technology for high-resolution flexible displays and solid state lighting, attracting intense scientific and industrial interest.

Contenu apparenté

L'électronique organique utilise des conducteurs et des semiconducteurs organiques pour les applications du type cellules photovoltaïques organiques, diodes électroluminescentes organiques (OLED) et transistors à effet de champ organiques (OFET).

Organic electronics utilizes organic conductors and semiconductors for applications in organic photovoltaics, organic light-emitting diodes, and organic field-effect transistors.

Questions

1–2 sur 2 questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 réponse
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 réponse
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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