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761001

Sigma-Aldrich

Lithium nickel manganese cobalt oxide

greener alternative

powder, <0.5 μm particle size, >98%

Synonyme(s) :

NMC

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About This Item

Formule linéaire :
LiNi0.33Mn0.33Co0.33O2
Numéro CAS:
Numéro MDL:
Code UNSPSC :
26111700
Nomenclature NACRES :
NA.23
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Qualité

battery grade

Essai

>98%

Forme

powder

Poids mol.

Mw 96.46 g/mol

Composition

LiNi0.33Mn0.33Co0.33O2

Caractéristiques du produit alternatif plus écologique

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Taille des particules

<0.5 μm

Pf

>290 °C (lit.)

Densité

2.11 g/cm3

Application(s)

battery manufacturing

Autre catégorie plus écologique

Description générale

Lithium nickel manganese cobalt oxide (NMC) is a class of electrode material that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.[1][2][3][4]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

NMC is a novel lithium insertion electrode material for advanced lithium-ion batteries. Mn doping significantly increases the thermal stability besides increasing the electrochemical charge-discharge behavior.
NMC111 (lithium nickel-manganese-cobalt oxide with a stoichiometry of 1:1:1) is a promising cathode material used in advanced lithium-ion batteries, particularly for electric vehicle applications, due to its high energy density and long cycle life. NMC111 powder has a layered crystal structure that enables efficient, reversible lithium-ion diffusion, which is essential for good electrochemical performance. Manganese doping improves the thermal stability of the material while enhancing its electrochemical charge-discharge behavior. Compared to other NMC materials, NMC111 has a higher thermal stability and is less prone to thermal runaway, making it a safer option for battery applications.

Caractéristiques et avantages

Our NMC111 has engineered improvements over other LiNMC materials including thermal stability and high conductivity:
  • More Reliable
  • Longer Cycle Life
  • Bulk and Pilot Scale Available

Informations légales

Product of Engi-Mat Co.

Pictogrammes

Health hazardExclamation mark

Mention d'avertissement

Warning

Mentions de danger

Classification des risques

Carc. 2 - Skin Sens. 1

Code de la classe de stockage

13 - Non Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


Listes réglementaires

Les listes réglementaires sont principalement fournies pour les produits chimiques. Seules des informations limitées peuvent être fournies ici pour les produits non chimiques. L'absence d'indication signifie qu'aucun des composants n'est répertorié. Il incombe à l'utilisateur de s'assurer de l'utilisation sûre et légale du produit.

EU REACH Annex XVII (Restriction List)


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Certificats d'analyse (COA)

Lot/Batch Number

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

A bi-functional lithium difluoro (oxalato) borate additive for lithium cobalt oxide/lithium nickel manganese cobalt oxide cathodes and silicon/graphite anodes in lithium-ion batteries at elevated temperatures
Lee SJ, et al.
Electrochimica Acta, 137, 1-8 (2014)
Belharouak, I.; et al.
Journal of Power Sources, 123, 247-247 (2003)
Impedance change and capacity fade of lithium nickel manganese cobalt oxide-based batteries during calendar aging
Schmitt J, et al.
Journal of Power Sources, 353, 183-194 (2017)
Choi, J.; Manthiram, A.; J.
Journal of the Electrochemical Society, 152, A1714-A1714 (2005)
The Li-ion rechargeable battery: a perspective
Goodenough JB and Park K
Journal of the American Chemical Society, 135(4), 1167-1176 (2013)

Articles

Professor Qiao's review explores stable microstructures for lithium metal fluoride batteries, advancing energy storage technologies.

Solid oxide fuel cells and electrolyzers show potential for chemical-to-electrical energy conversion, despite early development stages.

Li-ion batteries are currently the focus of numerous research efforts with applications designed to reduce carbon-based emissions and improve energy storage capabilities.

Lithium-ion batteries offer high energy density and cyclic performance for portable electronic devices.

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Questions

1–2 sur 2 questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 réponse
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 réponse
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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