391271

3-Methyl-1-indanone

99%

• Formule empirique (notation de Hill): C₁₀H₁₀O
• Numéro CAS: 6072-57-7
• Poids moléculaire : 146.19
• Numéro MDL: MFCD00156725
• Code UNSPSC : 12352100
• ID de substance PubChem : 24864370
• Nomenclature NACRES : NA.22

Propriétés

• Essai: 99%
• Forme: liquid
• Indice de réfraction: n20/D 1.558 (lit.)
• pb: 70-72 °C/0.7 mmHg (lit.)
• Densité: 1.075 g/mL at 25 °C (lit.)
• Groupe fonctionnel: ketone
• Chaîne SMILES: CC1CC(=O)c2ccccc12
• InChI: 1S/C10H10O/c1-7-6-10(11)9-5-3-2-4-8(7)9/h2-5,7H,6H2,1H3
• Clé InChI: XVTQSYKCADSUHN-UHFFFAOYSA-N

Description

Description générale

3-Methyl-1-indanone is a derivative of 1-indanone.Its synthesis has been reported.[1] The ¹H and ¹³C-NMR spectra of 3-methyl-1-indanone has been reported.[2] Biocatalyzed oxidation of racemic 3-methyl-1-indanone with high enanatioselectivity has been investigated.[3]

Application

3-Methyl-1-indanone is suitable for the synthesis of branched alkyl indanes (BINs).[4] It may be used in the following studies:

• Synthesis of 2,2,3-tribromo-2,3-dihydro-3-methylinden-1-one and 2-bromo-3-bromomethyl-1H-inden-1-one.[5]
• As photosensitizers for the splitting of dimethylthymine dimers.[6]
• As a model to verify three-phase model in enantioselective gas-liquid chromatography.[7]
• (-)-(R)-3-methyl-1-indanone may be used as standard for comparing the optical rotatory dispersion curve with 1,3-dialkylindenes in the study of base-catalyzed 1,3 proton transfer in indene systems.[8]
• As an optically active sensitizer to induce asymmetry in trans-1,2-diphenylcylcopropane (DPC).[9]
• The dl-isomers of 3-methyl-1-indanone may be used in the synthesis of monomeric and trimeric 3-methyl-1-indanethione.[10]

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)