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377171

Sigma-Aldrich

1,2-Epoxyhexane

97%

Synonyme(s) :

1-Hexene oxide, Butyloxirane

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About This Item

Formule empirique (notation de Hill) :
C6H12O
Numéro CAS:
1436-34-6
Poids moléculaire :
100.16
Beilstein:
102568
Numéro CE :
215-864-6
Numéro MDL:
MFCD00005154
Code UNSPSC :
12162002
ID de substance PubChem :
24863209
Nomenclature NACRES :
NA.23
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Niveau de qualité

100

Essai

97%

Forme

liquid

Impuretés

<3% acetic acid

Indice de réfraction

n20/D 1.406 (lit.)

pb

118-120 °C (lit.)

Densité

0.831 g/mL at 25 °C (lit.)

Température de stockage

2-8°C

Chaîne SMILES 

CCCCC1CO1

InChI

1S/C6H12O/c1-2-3-4-6-5-7-6/h6H,2-5H2,1H3

Clé InChI

WHNBDXQTMPYBAT-UHFFFAOYSA-N

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Catégories apparentées

Application

  • Poly (epichlorohydrin-co-1, 2-epoxyhexane)–a promising precursor for an energetic azido polymer for cast-cure: Discusses the synthesis of a copolymer using epichlorohydrin and 1,2-epoxyhexane, aiming to develop an internal plasticizer for energetic applications (TM Klapötke, 2016).
  • Synthesis of hierarchically porous zeolite TS-1 with small crystal size and its performance of 1-hexene epoxidation reaction: This study investigates the catalytic performance of 1,2-epoxyhexane in the preparation of intermediates for various chemical industries (M Zhang et al., 2021).
  • Bioproduction of Chiral Epoxyalkanes using Styrene Monooxygenase from Rhodococcus sp. ST‐10 (RhSMO): Focuses on the enzymatic production of (S)-1,2-epoxyhexane using a biocatalyst, highlighting its potential in creating chiral epoxyalkanes (H Toda et al., 2014).
  • Silica islands regulated external Ti‐site environment of TS‐1 for enhanced performance of 1‐hexene epoxidation: Explores the use of modified TS-1 catalysts to improve the selectivity and performance of 1,2-epoxyhexane in epoxidation reactions (J Yuan et al., 2023).
  • Gas-phase Photocatalytic Oxidation of 1-Hexene Using Heterogeneous Semiconductor Materials: Describes the synthesis of 1,2-epoxyhexane through gas-phase photocatalytic oxidation, focusing on the selectivity and efficiency of the process (EA Kamba et al., 2023).

Pictogrammes

FlameExclamation mark
GHS02,GHS07

Mention d'avertissement

Danger

Mentions de danger

H225,H302,H315,H319,H335

Classification des risques

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

59.0 °F - closed cup

Point d'éclair (°C)

15 °C - closed cup

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificats d'analyse (COA)

Lot/Batch Number
STBL0611
STBK8559
STBL0016
STBK1062
STBH2749

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

W J Choi et al.
Applied microbiology and biotechnology, 54(5), 641-646 (2000-12-29)
A two-phase membrane bioreactor was developed to continuously produce enantiopure epoxides using the epoxide hydrolase activity of Rhodotorula glutinis. An aqueous/organic cascade, hydrophilic, hollow-fiber membrane bioreactor was used: (1) to carry out large-scale resolution of epoxides, (2) to continuously extract
Ijaz Gul et al.
Journal of biotechnology, 311, 19-24 (2020-02-19)
Halohydrin dehalogenases (HHDHs) are valuable biocatalysts involved in the synthesis of β-substituted alcohols via their nucleophile-mediated ring-opening activity. To use directed evolution to unleash the latent potential of HHDHs for the synthesis of β-substituted alcohols, we report a high-throughput assay
Allison C Vander Wall et al.
Environmental science. Processes & impacts, 22(1), 66-83 (2019-11-02)
Secondary organic aerosol (SOA) particles are ubiquitous in air and understanding the mechanism by which they grow is critical for predicting their effects on visibility and climate. The uptake of three organic nitrates into semi-solid SOA particles formed by α-pinene
Thomas Klein et al.
Dalton transactions (Cambridge, England : 2003), 49(28), 9820-9834 (2020-07-08)
Al nanoparticles represent one of the most challenging classes of metal nanoparticles in synthesis and handling due to their high chemical reactivity and their affinity to oxidation. A promising wet chemical preparation route is the catalytic decomposition of alane adducts.
Zhimin Xue et al.
Chemistry, an Asian journal, 12(17), 2271-2277 (2017-06-20)
Development of inexpensive, easily prepared, non-toxic, and efficient catalysts for the cycloaddition of CO
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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 réponse

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 réponse

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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