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209694

Sigma-Aldrich

Ruthenium

powder, −200 mesh, 99.9% trace metals basis

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About This Item

Formule empirique (notation de Hill):
Ru
Numéro CAS:
7440-18-8
Poids moléculaire :
101.07
Numéro CE :
231-127-1
Numéro MDL:
MFCD00011207
Code UNSPSC :
12141739
ID de substance PubChem :
24852587
Nomenclature NACRES :
NA.23

Pureté

99.9% trace metals basis

Forme

powder

Résistivité

7.1 μΩ-cm, 0°C

Taille des particules

−200 mesh

Point d'ébullition

3900 °C (lit.)

Pf

2310 °C (lit.)

Densité

12.45 g/cm3 (lit.)

Chaîne SMILES 

[Ru]

InChI

1S/Ru

Clé InChI

KJTLSVCANCCWHF-UHFFFAOYSA-N

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Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Rafael E Rodríguez-Lugo et al.
Nature chemistry, 5(4), 342-347 (2013-03-21)
The development of an efficient catalytic process that mimics the enzymatic function of alcohol dehydrogenase is critical for using biomass alcohols for both the production of H2 as a chemical energy carrier and fine chemicals under waste-free conditions. Dehydrogenation of
Direct synthesis of pyrroles by dehydrogenative coupling of β-aminoalcohols with secondary alcohols catalyzed by ruthenium pincer complexes.
Dipankar Srimani et al.
Angewandte Chemie (International ed. in English), 52(14), 4012-4015 (2013-03-08)
Mette T Petersen et al.
Organic letters, 15(8), 1986-1989 (2013-04-05)
A series of 5-substituted 2-pyrrolidinones was synthesized through a one-pot ruthenium alkylidene-catalyzed tandem RCM/isomerization/nucleophilic addition sequence. The intermediates resulting from RCM/isomerization showed reactivity toward electrophiles in aldol condensation reactions which provided a new entry for the total synthesis of the
Jérôme Le Nôtre et al.
ChemSusChem, 6(4), 693-700 (2013-03-05)
A highly efficient procedure for obtaining resin-grade isoidide through catalytic epimerization of isosorbide using a ruthenium-on-carbon (Ru/C) catalyst is reported. A comprehensive reaction-parameter variation study involving substrate concentration, catalyst (type of metal, support, and loading), initial pH value, hydrogen pressure
Lipeng Wu et al.
Journal of the American Chemical Society, 135(10), 3989-3996 (2013-02-20)
An efficient and regioselective ruthenium-catalyzed hydroaminomethlyation of olefins is reported. Key to success is the use of specific 2-phosphino-substituted imidazole ligands and triruthenium dodecacarbonyl as catalyst. Both industrially important aliphatic as well as various functionalized olefins react with primary and
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