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10029

Sigma-Aldrich

Mercury(II) sulfate

puriss., ≥98%

Synonym(s):

Mercuric sulfate

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About This Item

Linear Formula:
HgSO4
CAS Number:
7783-35-9
Molecular Weight:
296.65
EC Number:
231-992-5
MDL number:
MFCD00011047
UNSPSC Code:
12352302
PubChem Substance ID:
329748123
NACRES:
NA.55

grade

puriss.

Assay

≥98%

form

powder or crystals

ign. residue (after red. with HCOOH)

≤0.1% (as SO4)

anion traces

chloride (Cl-): ≤50 mg/kg

cation traces

Fe: ≤50 mg/kg

SMILES string

[Hg++].[O-]S([O-])(=O)=O

InChI

1S/Hg.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2

InChI key

DOBUSJIVSSJEDA-UHFFFAOYSA-L

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Application

Mercury(II) sulfate can be used as a catalyst in the presence of sulfuric acid (H2SO4) for the:
  • Direct oxidation of methane to methanol.
  • Hydration of alkynes to the corresponding carbonyl compounds.
  • Conversion of alkyl protected glycals into their corresponding α,β-unsaturated enals (Perlin aldehydes).

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Target Organs

Kidney

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Laurie F Caslake et al.
Applied and environmental microbiology, 70(2), 1145-1150 (2004-02-10)
Contaminated water causes an estimated 6 to 60 billion cases of gastrointestinal illness annually. The majority of these cases occur in rural areas of developing nations where the water supply remains polluted and adequate sanitation is unavailable. A portable, low-cost
Direct oxidation of methane to methanol by mercuric sulfate catalyst.
Gang X, et al.
J. Catal., 196(2), 287-292 (2000)
Tariq SA and Hill JO.
J. Therm. Anal., 212, 277-281 (1981)
Catalysis by mercuric ion of reactions of glycals with water.
Gonzalez F, et al.
Carbohydrate Research, 42(2), 267-274 (1975)
Ai-hua Liang et al.
Zhongguo Zhong yao za zhi = Zhongguo zhongyao zazhi = China journal of Chinese materia medica, 30(4), 249-252 (2005-02-24)
Traditional Chinese medicine (TCM) experienced a gradual course in recognition of the toxicity of Cinnabaris from "nontoxic" to "toxic". The ancient doctors of TCM understood both the toxic property and the regularity of increasing toxicity of Cinnabaris. In long-term clinical
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