14520
Tin(IV) chloride
fuming, ≥99%
Synonym(s):
Stannic chloride
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About This Item
Linear Formula:
SnCl4
CAS Number:
Molecular Weight:
260.52
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
Pricing and availability is not currently available.
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Quality Level
Assay
≥99%
reaction suitability
reagent type: catalyst
core: tin
density
2.217 g/mL at 20 °C (lit.)
anion traces
sulfate (SO42-): ≤100 mg/kg
cation traces
As: ≤50 mg/kg
Fe: ≤10 mg/kg
SMILES string
Cl[Sn](Cl)(Cl)Cl
InChI
1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
InChI key
HPGGPRDJHPYFRM-UHFFFAOYSA-J
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Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Evangelina Repetto et al.
Bioorganic & medicinal chemistry, 17(7), 2703-2711 (2009-03-14)
Thiodisaccharides having beta-D-Galf or alpha-L-Araf units as non-reducing end have been synthesized by the SnCl(4)- or MoO(2)Cl(2)-promoted thioglycosylation of per-O-benzoyl-D-galactofuranose (1), its 1-O-acetyl analogue 4, or per-O-acetyl-alpha-L-arabinofuranose (16) with 6-thioglucose or 6-thiogalactose derivatives. After convenient removal of the protecting groups
Yu-Jun Zhao et al.
Journal of the American Chemical Society, 130(30), 10024-10029 (2008-07-09)
New strategies using chiral acetal or chiral mixed-acetal in the presence of Lewis acids (SnCl4 or TiCl4) to promote polyene cyclization reaction are described. Acetal-promoted and mixed-acetal-promoted polyene cyclization products are very versatile and can easily be converted into various
Isabelle Bonhoure et al.
Environmental science & technology, 37(10), 2184-2191 (2003-06-06)
In this study, the immobilization mechanisms of Sn(IV) onto calcium silicate hydrates (C-S-H) and hardened cement paste (HCP) have been investigated by combining wet chemistry experiments with X-ray absorption spectroscopy (XAS). Evidence is presented which demonstrates the formation of a
Leo A Paquette et al.
The Journal of organic chemistry, 69(22), 7442-7447 (2004-10-23)
Tin tetrachloride-catalyzed glycosidation of persilylated nucleobases with acetate donor 6 in CH(2)Cl(2) solution followed by deprotection gave rise very predominantly to alpha-spironucleosides. These stereochemical assignments stem from the determination of NOE interactions and an X-ray crystallographic analysis of the latter
Andreas T Messmer et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(47), 14989-14995 (2012-10-04)
Determining the structure of reactive intermediates is the key to understanding reaction mechanisms. To access these structures, a method combining structural sensitivity and high time resolution is required. Here ultrafast polarization-dependent two-dimensional infrared (P2D-IR) spectroscopy is shown to be an
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