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G5809

Sigma-Aldrich

Glycidol

96%

Synonym(s):

(±)-Glycidol, (±)-Oxirane-2-methanol, 2,3-Epoxy-1-propanol, Glycerolglycide

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About This Item

Empirical Formula (Hill Notation):
C3H6O2
CAS Number:
Molecular Weight:
74.08
Beilstein:
383562
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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vapor density

2.15 (vs air)

Quality Level

vapor pressure

0.9 mmHg ( 25 °C)

Assay

96%

form

liquid

autoignition temp.

780 °F

impurities

≤2% diglycidyl ether

refractive index

n20/D 1.433 (lit.)

bp

61-62 °C/15 mmHg (lit.)

density

1.117 g/mL at 25 °C (lit.)

shipped in

wet ice

storage temp.

2-8°C

SMILES string

OCC1CO1

InChI

1S/C3H6O2/c4-1-3-2-5-3/h3-4H,1-2H2

InChI key

CTKINSOISVBQLD-UHFFFAOYSA-N

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Application

Glycidol has been used in the synthesis of hyperbranched polyglycerol (hPG) via ring opening reaction. These hPGs are being considered as alternatives to PEGs for developing antifouling surfaces due to their thermal and oxidative stability.[1] It can also be used in the synthesis of ethoxy ethyl glycidyl ether.[2] Glycidol may also be used in the preparation of chelating polymers for borate removal.[3][4]

Pictograms

Skull and crossbonesHealth hazard

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

161.6 °F

Flash Point(C)

72 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Removal of trace boron from aqueous solution using iminobis-(propylene glycol) modified chitosan beads.
Gazi M
Reactive functional Polymers, 72(10), 680-686 (2012)
Development of Antifouling Hyperbranched Polyglycerol Layers on Hydroxyl Poly-p-xylylene Coatings.
Chen P
Langmuir, 33(51), 14657-14662 (2017)
Jenny Aasa et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 128, 54-60 (2019-03-28)
Here we evaluate a multiplicative (relative) risk model for improved cancer risk estimation of genotoxic compounds. According to this model, cancer risk is proportional to the background tumor incidence and to the internal dose of the genotoxic compound. Furthermore, the
Polyglycidol-block-poly (ethylene oxide)-block-polyglycidol: synthesis and swelling properties.
Dworak A
Reactive functional Polymers, 42(1), 31-36 (1999)
C Crews et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 30(1), 11-45 (2012-10-02)
Esters of 2 - and 3-monochloropropane-1,2-diol (MCPD) and glycidol esters are important contaminants of processed edible oils used as foods or food ingredients. This review describes the occurrence and analysis of MCPD esters and glycidol esters in vegetable oils and

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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