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766127

Sigma-Aldrich

2,5-Dilfuoro-4-methoxyphenylzinc bromide solution

0.6 M in THF

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About This Item

Empirical Formula (Hill Notation):
C7H5BrF2OZn
Molecular Weight:
288.40
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22

form

liquid

reaction suitability

core: zinc
reagent type: catalyst
reaction type: Negishi Coupling

reagent type: derivatization reagent
reaction type: Negishi Coupling

concentration

0.6 M in THF

density

1.029 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

COc1cc(F)c([Zn]Br)cc1F

InChI

1S/C7H5F2O.BrH.Zn/c1-10-7-4-5(8)2-3-6(7)9;;/h3-4H,1H3;1H;/q;;+1/p-1

InChI key

WEUAQJYCDOJDPB-UHFFFAOYSA-M

Application

Nucleophlic reagent applicable for substitution and addition reactions. Also could be used in cross coupling reactions (Negishi couplings).

Organozinc Reagents

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-4.0 °F

Flash Point(C)

-20 °C


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