703095

Hydrogen[4-[bis(2,4,6-trimethylphenyl)phosphino]-2,3,5,6-tetrafluorophenyl]hydrobis(2,3,4,5,6-pentafluorophenyl)borate

95%

• Synonym(s): Frustrated phosphonium borate 2, Hydrogen[4-[dimesitylphosphino]-2,3,5,6-tetrafluorophenyl]hydrobis(2,3,4,5,6-pentafluorophenyl)borate
• Linear Formula: H⁺[(((CH₃)₃C₆H₂)₂PC₆F₄)B(H) (C₆F₅)₂]⁻
• CAS Number: 918824-12-1
• Molecular Weight: 764.34
• MDL number: MFCD16621393
• UNSPSC Code: 12352300

Properties

• Assay: 95%
• mp: 211-216 °C
• storage temp.: 2-8°C
• SMILES string: Cc1cc(C)c([PH+](c2c(C)cc(C)cc2C)c3c(F)c(F)c([BH-](c4c(F)c(F)c(F)c(F)c4F)c5c(F)c(F)c(F)c(F)c5F)c(F)c3F)c(C)c1
• InChI: 1S/C36H23BF14P/c1-11-7-13(3)34(14(4)8-11)52(35-15(5)9-12(2)10-16(35)6)36-32(50)24(42)19(25(43)33(36)51)37(17-20(38)26(44)30(48)27(45)21(17)39)18-22(40)28(46)31(49)29(47)23(18)41/h7-10,37H,1-6H3/q-1/p+1
• InChI key: IENZHWXRYKZMGT-UHFFFAOYSA-O

Description

Application

Catalyst for metal-free hydrogenation

Reactant for:

• Formation of phosphine-boranes and cationic phosphonium-boranes
• Metal-free hydrogen activation

Frustrated phosphonium borate for metal-free catalytic hydrogenation of imines. Activates dihydrogen under mild conditions.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable