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682950

Sigma-Aldrich

1,1′-Bis[(11bR)-dinaphtho[2,1-d:1′, 2′-f][1,3,2]dioxaphosphepin-4-yl]ferrocene

Synonym(s):

R, R-Reetz F-Diphosphonite

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About This Item

Empirical Formula (Hill Notation):
C50H32FeO4P2
CAS Number:
Molecular Weight:
814.58
MDL number:
UNSPSC Code:
12352000

SMILES string

[Fe].[CH]1[CH][CH][C]([CH]1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56.[CH]7[CH][CH][C]([CH]7)P8Oc9ccc%10ccccc%10c9-c%11c(O8)ccc%12ccccc%11%12

Application

Used in a variety of asymmetric reactions, including: hydrogenations and conjugate additions.

Certificates of Analysis (COA)

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Reetz, M. T.
Pure and Applied Chemistry. Chimie Pure Et Appliquee, 71, 1503-1503 (1999)
Reetz, M. T. et al.
Chemical Communications (Cambridge, England), 2077-2077 (1998)

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