664995
Chlorodihydrido[bis(2-diisopropylphosphino)ethylamine]iridium(III), mixture of isomers
97%
Synonym(s):
[2-[bis(1-methylethyl)phosphino-KP]-N-[2-[bis(1-methylethyl)phosphino-KP]ethyl]ethanamine-KN]chlorodihydroiridium
About This Item
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Assay
97%
form
solid
reaction suitability
core: iridium
reagent type: catalyst
mp
248-253 °C
SMILES string
Cl[IrH2].CC(C)P(CCNCCP(C(C)C)C(C)C)C(C)C
InChI
1S/C16H37NP2.ClH.Ir.2H/c1-13(2)18(14(3)4)11-9-17-10-12-19(15(5)6)16(7)8;;;;/h13-17H,9-12H2,1-8H3;1H;;;/q;;+1;;/p-1
InChI key
QPAONQONOKDMMJ-UHFFFAOYSA-M
Application
- Preparation of aliphatic amine derivatives via amination of alcohols and diols with amines
- Hydrogenation of ketones, diketones, unsaturated ketones and aldehydes
Legal Information
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Articles
An increased interest in aminophosphine type ligands used for asymmetric synthesis has been witnessed. This growth in popularity of aminophosphine ligands in asymmetric synthesis is in part due to the growing number of convenient synthetic pathways leading to useful ligand sets.
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