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Sigma-Aldrich

9-Phenyl-9-fluorenol

99%

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About This Item

Empirical Formula (Hill Notation):
C19H14O
CAS Number:
Molecular Weight:
258.31
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
form:
solid
Assay:
99%

Assay

99%

form

solid

mp

93-95 °C (lit.)

functional group

hydroxyl
phenyl

SMILES string

OC2(c1ccccc1)c3ccccc3-c4ccccc24

InChI

1S/C19H14O/c20-19(14-8-2-1-3-9-14)17-12-6-4-10-15(17)16-11-5-7-13-18(16)19/h1-13,20H

InChI key

UJPHBDAPVWFPTG-UHFFFAOYSA-N

General description

9-Phenyl-9-fluorenol is a fluorine derivative. It is formed as intermediate during the synthesis of 9-bromo-9-phenylfluorene.[1] Competitive interactions in crystalline 9-phenyl-9-fluorenol has been reported.[2] Spectral properties of 9-phenyl-9-fluorenol have been investigated.[3] 9-Phenyl-9-fluorenol is reported as bichromphoric fluorine derivative and its absorption and emission characteristics have been investigated in non-polar and polar solvents at different temperatures.[4]

Application

9-Phenyl-9-fluorenol may be used as reagent in the synthesis of trisphosphine alkoxide complexes.[5] It may be useful in the preparation of 2,2′-biphenol monobenzoate[6] and is a convenient source of the 9-phenylfluorenyl cation.[7]

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Tetrahedron Letters, 24, 71-71 (1983)
Journal of the Chemical Society. Perkin Transactions 1, 931-931 (1989)
Competitive interactions in crystalline 9-pyridyl-9-fluorenols: crossover from O-HO to O-HN hydrogen bonding to construct intra-and intermolecular, helical and linear contact modes.
Hosseinzadeh R, et al.
CrystEngComm, 11(7), 1331-1337 (2009)
Spectral and photophysical properties of the bi-chromophoric fluorene derivatives.
Redzimski T and Heldt JR.
Journal of Molecular Structure, 734(1), 197-205 (2005)
9-Bromo-9Phenylfluorene.
Jamison TF, et al.
Organometallic Syntheses, 220-220 (1993)

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