333557

(1-Bromovinyl)trimethylsilane

97%

• Synonym(s): α-(Trimethylsilyl)vinyl bromide
• Linear Formula: H₂C=C(Br)Si(CH₃)₃
• CAS Number: 13683-41-5
• Molecular Weight: 179.13
• Beilstein: 1742258
• EC Number: 237-195-9
• MDL number: MFCD00014927
• UNSPSC Code: 12352100
• PubChem Substance ID: 24860146
• NACRES: NA.22

Properties

• vapor density: >1 (vs air)
• Assay: 97%
• form: liquid
• refractive index: n20/D 1.458 (lit.)
• bp: 124 °C/745 mmHg (lit.)
• density: 1.156 g/mL at 25 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: C[Si](C)(C)C(Br)=C
• InChI: 1S/C5H11BrSi/c1-5(6)7(2,3)4/h1H2,2-4H3
• InChI key: VVDJVCJVVHHCIB-UHFFFAOYSA-N

Description

General description

Tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reactions of (1-bromovinyl)trimethylsilane with organozinc bromides were studied.

Safety Information

• Pictograms: GHS02
• Signal Word: Danger
• Hazard Statements: H225
• Precautionary Statements: P210
• Hazard Classifications: Flam. Liq. 2
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): 55.4 °F - closed cup
• Flash Point(C): 13 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves