Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

29580

Sigma-Aldrich

cis,cis-1,5-Cyclooctadiene

≥98.0% (GC)

Synonym(s):

COD

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C8H12
CAS Number:
1552-12-1
Molecular Weight:
108.18
Beilstein:
1209288
EC Number:
216-291-4
MDL number:
MFCD00001752
UNSPSC Code:
12352100
PubChem Substance ID:
57648379

Assay

≥98.0% (GC)

refractive index

n20/D 1.493

solubility

water: soluble 0.05 g/L

density

0.880 g/mL at 20 °C (lit.)

SMILES string

C1CC=CCCC=C1

InChI

1S/C8H12/c1-2-4-6-8-7-5-3-1/h1-2,7-8H,3-6H2/b2-1-,8-7-

InChI key

VYXHVRARDIDEHS-QGTKBVGQSA-N

General description

Surface grafting of cis,cis-1,5-cyclooctadiene (cyclic olefin) with low strain energy was explored using ring-opening metathesis polymerization in the vapor phase[1]. The inclusion complex of cis,cis-1,5-cyclooctadiene with β-cyclodextrin (β-CD) was studied by using proton NMR spectroscopy[2].

Application

cis,cis-1,5-Cyclooctadiene (COD) has been employed as ligand:
  • during regio- and stereoselective synthesis of (Z)-1,2-dihaloalkenes[3]
  • in the preparation of metal complexes, e.g. bis-COD-nickel, a versatile reagent for preparing (PI)-allylnickel halides[4]

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 3

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

89.6 °F - closed cup

Flash Point(C)

32 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
BCBL2155V
1369462V
1369462
332796/1
1204708

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

M.F. Semmelhack
Org. React., 19, 115-115 (1972)
Jhane Rose P Encarguez et al.
Environmental monitoring and assessment, 191(9), 532-532 (2019-08-04)
Macajalar Bay in the southern Philippines has become an attractive thoroughfare with recent developments, rendering anthropogenic input to the coastal waters. Expediting coastal resource management strategies necessitates the present study on coastal water characteristics. This was aided with distribution pattern
Ting Ma et al.
Science advances, 6(1), eaau3798-eaau3798 (2020-01-11)
Increased human activity threatens inland water quality in China. Major efforts have been made to alleviate water pollution since 2001. Understanding how water quality responds to these forces can help to guide future efforts to maintain water security and sustainability.
Maria Felisa Z Lerum et al.
Langmuir : the ACS journal of surfaces and colloids, 27(9), 5403-5409 (2011-04-08)
Surface grafting of cyclic olefins with low strain energies, including cyclopentene (CP), 1,4-cyclohexadiene (CHD), cycloheptene (CHP), cis-cyclooctene (CO), cis,cis-1,5-cyclooctadiene (COD), 1,3,5,7-cyclooctatetraene (COT), cyclododecene (CD), and trans,trans,cis-1,5,9-cyclododecatriene (CDT), was explored using ring-opening metathesis polymerization in the vapor phase. These monomers do
Cao Yujuan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 73(4), 713-718 (2009-04-22)
The inclusion behavior of cis-cyclooctene, cis, cis-1, 3-cyclooctadiene and cis, cis-1, 5-cyclooctadiene with beta-cyclodextrin (beta-CD) was studied by using (1)H NMR method in D(2)O/CD(3)OD solution and PM3 quantum-chemical simulation in vacuum. The experimental results indicate that each guest molecule penetrates
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service