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Key Documents

273406

Sigma-Aldrich

trans-α-Methylstilbene

99%

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About This Item

Linear Formula:
C6H5C(CH3)=CHC6H5
CAS Number:
Molecular Weight:
194.27
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

99%

form

solid

bp

285-286 °C (lit.)

mp

81-83 °C (lit.)

SMILES string

[H]\C(c1ccccc1)=C(\C)c2ccccc2

InChI

1S/C15H14/c1-13(15-10-6-3-7-11-15)12-14-8-4-2-5-9-14/h2-12H,1H3/b13-12+

InChI key

OVZXISBUYCEVEV-OUKQBFOZSA-N

Application

trans-α-Methylstilbene was used in the synthesis of enantiomerically pure imidazolium salts bearing an oxazoline unit[1].

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Steve Nanchen et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(17), 4550-4558 (2006-03-25)
Two libraries of enantiomerically pure imidazolium salts bearing an oxazoline unit were synthesized. Deprotonation of the imidazolium salts and complexation of the resulting oxazoline-carbene ligands to iridium(I) was achieved in one step by mixing the imidazolium salts with NaOtBu and

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