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106887

Sigma-Aldrich

Ferrocenecarboxylic acid

97%

Synonym(s):

(Carboxycyclopentadienyl)cyclopentadienyliron, Carboxyferrocene, Carboxylferrocene, Cyclopentadienecarboxylic acid, Ferrocenoic acid

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About This Item

Empirical Formula (Hill Notation):
C11H10FeO2
CAS Number:
1271-42-7
Molecular Weight:
230.04
EC Number:
215-040-6
MDL number:
MFCD00001430
UNSPSC Code:
12352300
PubChem Substance ID:
24846745
NACRES:
NA.22

Assay

97%

reaction suitability

core: iron
reagent type: catalyst

mp

210 °C (dec.) (lit.)

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.OC(=O)[C]2[CH][CH][CH][CH]2

InChI

1S/C6H5O2.C5H5.Fe/c7-6(8)5-3-1-2-4-5;1-2-4-5-3-1;/h1-4H,(H,7,8);1-5H;

InChI key

VUJLGCHOGQEAED-UHFFFAOYSA-N

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General description

Papanicolaou is a widely used stain in cytopathology. It is a polychrome stain that has the ability to stain several constituents of cell differentially due to the presence of multiple dyes. Papanicolaou stain consists of a basic dye, haematoxylin that stains the nucleus and three acid dyes like light green, eosin and orange G that stain the cytoplasm.

Application

Used to esterify complex mixtures of phenols and alcohols for analysis by GCMS.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Huiqin Yao et al.
The journal of physical chemistry. B, 113(49), 16021-16027 (2009-11-17)
Concanavalin A (Con A) and dextran (Dex) were assembled into {Con A/Dex}(n) layer-by-layer films on electrodes by the biospecific interaction between them. At {Con A/Dex}(n) film electrodes, the cyclic voltammetric (CV) response of different electroactive probes, such as Fe(CN)(6)(3-), Ru(NH(3))(6)(3+)
Cedric L Hugelshofer et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 22(42), 15125-15136 (2016-09-08)
We present a full account of the development of a strategy that culminated in the first total syntheses of the unique oxetane-containing natural product (+)-dictyoxetane and the macrocyclic diterpene (+)-dolabellane V. Our retrosynthetic planning was guided by both classical and nonconventional
Frank A H Wasinski et al.
Journal of chromatography. A, 1157(1-2), 376-385 (2007-05-22)
Phenols and alcohols in complex petrochemical samples are derivatized to esters of ferrocene carboxylic acid in a rapid and simple reaction. These esters show several characteristic ions of high intensity in gas chromatography coupled with electron impact ionization mass spectrometry
Huilan Su et al.
Biosensors & bioelectronics, 26(11), 4601-4604 (2011-05-31)
A multiple amplification immunoassay was proposed to detect alpha-fetoprotein (AFP), which was based on ferrocenemonocarboxylic-HRP conjugated on Pt nanoparticles as labels for rolling circle amplification (RCA). Firstly, the capture antibody (anti-AFP) was immobilized on glass carbon electrode (GCE) deposited nano-sized
Shunichi Fukuzumi et al.
Chemical communications (Cambridge, England), 48(79), 9801-9815 (2012-07-07)
Anion binding has emerged as an attractive strategy to construct supramolecular electron donor-acceptor complexes. In recent years, the level of sophistication in the design of these systems has advanced to the point where it is possible to create ensembles that
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