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C3654

Sigma-Aldrich

Ammonium cerium(IV) nitrate

≥98% (titration)

Synonym(s):

Ceric ammonium nitrate

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About This Item

Linear Formula:
Ce(NH4)2(NO3)6
CAS Number:
16774-21-3
Molecular Weight:
548.22
EC Number:
240-827-6
MDL number:
MFCD00151121
UNSPSC Code:
12352302
PubChem Substance ID:
329775041
NACRES:
NA.55
grade:
for analytical purposes
form:
powder or crystals
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grade

for analytical purposes

Assay

≥98% (titration)

form

powder or crystals

reaction suitability

reagent type: oxidant

pH

0.61 (20 °C, 111.11 g/L)

SMILES string

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI key

WIBGOERAEYJBOT-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW3421
MKCV6388
MKCS1750
MKCN1224
MKCJ2717

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David A Evans et al.
Organic letters, 8(24), 5669-5671 (2006-11-17)
The ceric ammonium nitrate promoted oxidations of 4,5-diphenyloxazoles and oxazoles with various substitution patterns have been investigated. This transformation results in the formation of the corresponding imide in good yield and tolerates a wide variety of functional groups and substituents
Ahmad Shaabani et al.
Chemical & pharmaceutical bulletin, 56(1), 79-81 (2008-01-08)
The direct conversion of alpha-hydroxy ketones and alpha-keto oximes into quinoxaline derivatives in the presence of a catalytic amount of ceric ammonium nitrate via metal-catalyzed aerobic oxidation followed by in situ trapping with aromatic 1,2-diamines in water as a green
Alexander M Jacobine et al.
The Journal of organic chemistry, 73(18), 7409-7412 (2008-08-13)
The generation of substituted gamma-lactones can be accomplished through application of a tandem chain extension-aldol reaction, followed by CAN-mediated oxidative cleavage of the aldol product. The oxidative cleavage requires the intermediacy of a hemiketal and the presence of an alpha-heteroatom.
Weibin Song et al.
Bioorganic & medicinal chemistry letters, 22(1), 387-390 (2011-11-26)
A new, practical and efficient method for the synthesis of anhydrovinblastine AVBL (1f) by oxidative coupling of vindoline and catharanthine in the presence of ceric ammonium nitrate (CAN) was developed. Under the optimized reaction conditions, we synthesized a new series
S Sudha et al.
Ultrasonics sonochemistry, 19(5), 994-998 (2012-03-09)
Tetrahydrobenzo[c]xanthenes-11-ones was synthesized by a three component reaction of α-naphthol, aromatic aldehyde and dimedone. Ceric ammonium nitrate acts as a suitable eco-friendly catalyst for this method. Shorter reaction duration, mild reaction condition and low cost make this protocol more effective.
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