517127

Dimethyl carbonate

anhydrous, ≥99%

• Synonym(s): DMC, Carbonic acid dimethyl ester
• Linear Formula: (CH₃O)₂CO
• CAS Number: 616-38-6
• Molecular Weight: 90.08
• Beilstein: 635821
• EC Number: 210-478-4
• MDL number: MFCD00008420
• UNSPSC Code: 12352108
• PubChem Substance ID: 57651340
• NACRES: NA.21

Properties

• grade: anhydrous
• Quality Level: 100
• vapor density: 3.1 (vs air)
• vapor pressure: 18 mmHg ( 21.1 °C)
• Assay: ≥99%
• form: liquid
• expl. lim.: 4.22-12.87 % (lit.)
• greener alternative product characteristics: Less Hazardous Chemical Syntheses; Safer Solvents and Auxiliaries; Design for Degradation; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• impurities: <0.002% water; <0.005% water (100mL pkg)
• color: APHA: <50
• refractive index: n20/D 1.368 (lit.)
• bp: 90 °C (lit.)
• mp: 2-4 °C (lit.)
• density: 1.069 g/mL at 25 °C (lit.)
• greener alternative category: Aligned,
• SMILES string: O=C(OC)OC
• InChI: 1S/C3H6O3/c1-5-3(4)6-2/h1-2H3
• InChI key: IEJIGPNLZYLLBP-UHFFFAOYSA-N

Description

General description

Dimethyl carbonate (DMC) is a versatile, non-toxic, biodegradable reagent with tunable chemical reactivity. It serves as a green alternative to dimethyl sulfate or methyl halides and phosgene for methylation and carboxylation reactions. DMC can be prepared by the base-catalyzed reaction between carbon dioxide and methanol.

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Application

Dimethyl carbonate has been used to dissolve poly (lactic-co-glycolic acid) (PLGA) to form PLGA-coated bioactive glass-ceramic scaffolds.

Features and Benefits

Greener solvent

Safety Information

• Pictograms: GHS02
• Signal Word: Danger
• Hazard Statements: H225
• Precautionary Statements: P210 - P233 - P240 - P241 - P242 - P243
• Hazard Classifications: Flam. Liq. 2
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 1
• Flash Point(F): 60.8 °F - closed cup
• Flash Point(C): 16 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves