531960

(R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminum chloride

• Synonym(s): (R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoaluminium(III) chloride
• Empirical Formula (Hill Notation): C₃₆H₅₂AlClN₂O₂
• CAS Number: 250611-13-3
• Molecular Weight: 607.24
• MDL number: MFCD02684547
• UNSPSC Code: 12352101
• PubChem Substance ID: 24877850
• NACRES: NA.22

Properties

• mp: 250-255 °C (lit.)
• Quality Level: 100
• SMILES string: CC(C)(C)c1cc2\C=N\[C@@H]3CCCC[C@H]3\N=C\c4cc(cc(c4O[Al](Cl)Oc2c(c1)C(C)(C)C)C(C)(C)C)C(C)(C)C
• InChI: 1S/C36H54N2O2.Al.ClH/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;;1H/q;+3;/p-3/b37-21+,38-22+;;/t29-,30-;;/m1../s1
• InChI key: KGVBCKDZFMLRMA-OHRASPNLSA-K

Description

Application

Catalyst for:

• Asymmetric iodolactonizations
• Cyanosilylation reactions
• Phospho-aldol catalysis

Legal Information

Sold under license from Sterling Pharma Solutions Limited.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H302 + H312 + H332
• Precautionary Statements: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves