31477
Bifenox
PESTANAL®, analytical standard
Synonym(s):
Methyl 5-(2,4-dichlorophenoxy)-2-nitrobenzoate
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About This Item
Empirical Formula (Hill Notation):
C14H9Cl2NO5
CAS Number:
Molecular Weight:
342.13
Beilstein:
2170169
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24
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grade
analytical standard
Quality Level
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
application(s)
agriculture
environmental
format
neat
SMILES string
COC(=O)c1cc(Oc2ccc(Cl)cc2Cl)ccc1[N+]([O-])=O
InChI
1S/C14H9Cl2NO5/c1-21-14(18)10-7-9(3-4-12(10)17(19)20)22-13-5-2-8(15)6-11(13)16/h2-7H,1H3
InChI key
SUSRORUBZHMPCO-UHFFFAOYSA-N
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Application
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
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Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Ana Catarina Almeida et al.
Aquatic toxicology (Amsterdam, Netherlands), 210, 117-128 (2019-03-09)
The widespread presence of herbicides in the aquatic environment has raised awareness about the need to develop further in depth ecotoxicological risk assessments, more specifically on potential effects on photosynthetic organisms as microalgae. The majority of the information available regarding
B M Francis
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 21(4), 303-317 (1986-08-01)
The teratogenicity of the diphenyl ether herbicide bifenox [2,4-dichlorophenyl 3'-carboxymethyl-4'-nitrophenyl ether] was compared to that of nitrofen [2,4-dichlorophenyl 4'-nitrophenyl ether] in rats and in mice. Neither compound increased prenatal mortality in mice. Because nitrofen causes both malformations that are compatible
K Siviková et al.
Mutation research, 439(2), 129-135 (1999-02-19)
The commercial herbicide with active element bifenox (principal tradename Modown) was tested for the evaluation of genotoxicity in cultured cow peripheral lymphocytes in vitro. Several cytogenetic endpoints as chromosome aberrations (CA), sister chromatid exchanges (SCE), mitotic (MI) and proliferation (PI)
D J Hoffman et al.
Journal of toxicology and environmental health, 34(3), 323-336 (1991-11-01)
Beginning the day after hatching, American kestrel (Falco sparverius) nestlings were orally dosed for 10 consecutive days with 5 microliters/g of corn oil (controls) or one of the diphenyl ether herbicides (nitrofen, bifenox, or oxyfluorfen) at concentrations of 10, 50
A Lubineau et al.
Carbohydrate research, 228(1), 191-203 (1992-04-10)
Glycosides (alpha- and beta-D-glucosides and -D-galactosides) derived from three pesticides, 2-tert-butyl-2,4-dinitrophenol,2,6-dibromo-4-cyanophenol, and 5-(2,4-dichlorophenoxy)-2-nitrobenzoic acid, were synthesized from 2,3,4,6-tetra-O-chloroacetyl-D-gluco- and -D-galactopyranose by use of the Mitsunobu reaction. It was shown that selectivity for the beta-D anomer increases with the pKa of
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