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516988

Sigma-Aldrich

Cesium hydroxide monohydrate

99.95% trace metals basis

Synonym(s):

2-Aminoethyl 2-methylacrylate hydrochloride, 2-Aminoethyl methacrylate hydrochloride, Methacrylic acid, 2-aminoethyl ester, hydrochloride

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About This Item

Empirical Formula (Hill Notation):
HCsO · H2O
CAS Number:
35103-79-8
Molecular Weight:
167.93
EC Number:
244-344-1
MDL number:
MFCD00010964
UNSPSC Code:
12352302
PubChem Substance ID:
24873911
NACRES:
NA.23

Assay

99.95% trace metals basis

form

powder

impurities

≤550.0 ppm Trace Metal Analysis

mp

272 °C (lit.)

density

3.68 g/mL at 25 °C (lit.)

SMILES string

[Cs+].[O-][H].[H]O[H]

InChI

1S/Cs.H2O/h;1H2/q+1;/p-1

InChI key

HUCVOHYBFXVBRW-UHFFFAOYSA-M

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General description

Cesium hydroxidemonohydrate is commonly used as a catalyst in many organic transformations andas an initiator in polymerization reactions.

Application

Cesium hydroxide monohydrate can be used as a catalyst in the synthesis of:
  • O-allenes and N-allenes via isomerization of terminal alkynes. This method allows the efficient synthesis of allenes in high yields under mild conditions with wide functional group tolerance.
  • Unsymmetrical bis-allyl ethers consist of an E-allylic unit and a terminal allylic unit via dimerization of Baylis-Hillman adducts.
Cesium hydroxide monohydrate can also be used as an initiator for the heterogeneous ring-opening polymerization of monosubstituted oxiranes.

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1A

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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