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Sigma-Aldrich

Benzyl methacrylate

96%, contains monomethyl ether hydroquinone as inhibitor

Synonym(s):

Benzyl α-methylacrylate, Benzyl 2-methylacrylate, Phenylmethyl 2-methyl-2-propenoate

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About This Item

Linear Formula:
H2C=C(CH3)CO2CH2C6H5
CAS Number:
Molecular Weight:
176.21
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Assay

96%

form

liquid

contains

monomethyl ether hydroquinone as inhibitor

refractive index

n20/D 1.512 (lit.)

bp

95-98 °C/4 mmHg (lit.)

density

1.04 g/mL at 25 °C (lit.)

SMILES string

CC(=C)C(=O)OCc1ccccc1

InChI

1S/C11H12O2/c1-9(2)11(12)13-8-10-6-4-3-5-7-10/h3-7H,1,8H2,2H3

InChI key

AOJOEFVRHOZDFN-UHFFFAOYSA-N

Application


  • Statistical copolymers of benzyl methacrylate and diethylaminoethyl methacrylate: monomer reactivity ratios and thermal properties: The synthesis of poly(benzyl methacrylate) (PBzMA) and poly(diethylaminoethyl methacrylate) (PDEAEMA) statistical copolymers via free radical polymerization (Theodosopoulos, 2015).

  • Poly (benzyl methacrylate)-poly triblock-copolymers as solid electrolyte for lithium batteries: Synthesis of a new type of BAB triblock copolymer based on benzyl methacrylate and oligo(ethylene glycol) methyl ether methacrylate for lithium battery electrolytes (Bergfelt et al., 2018).

  • Dilute Solution Properties of Poly (benzyl methacrylate) in Ionic Liquids: Study on the dilute solution properties of PBzMA in various ionic liquids (Kharel et al., 2020).

  • Synthesis and evaluation of benzyl methacrylate-methacrylate copolymers as pour point depressant in diesel fuel: Study on the effectiveness of benzyl methacrylate-methacrylate copolymers as pour point depressants in diesel fuel (Xie et al., 2019).

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

224.6 °F - closed cup

Flash Point(C)

107 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Qijing Chen et al.
Scientific reports, 7(1), 8493-8493 (2017-08-19)
A hydrophobic CCS polymer of poly(benzyl methacrylate) (PBzMA) was prepared in toluene by reversible addition-fragmentation chain transfer (RAFT)-mediated dispersion polymerization. The CCS polymer, with poly(benzyl methacrylate) as the arm and crosslinked N, N'-bis(acryloyl)cystamine (BAC) as the core, was confirmed by
So Jung Park et al.
ACS applied materials & interfaces, 12(43), 49165-49173 (2020-09-30)
Control of the cross-linking reaction is imperative when developing a sophisticated in situ forming hydrogel in the body. In this study, a heteroarmed thermoresponsive (TR) nanoparticle was designed to investigate the mechanism of controlling reactivity of the functional groups introduced
Yoshinori Arisaka et al.
Journal of biomaterials science. Polymer edition, 28(10-12), 974-985 (2017-04-13)
Sulfonated-polyrotaxane (PRX)-coated surfaces with tethered bone morphogenetic protein-2 (BMP-2) were designed for inducing osteogenic differentiation of MC3T3-E1 cells (preosteoblasts). Sulfonated-PRX triblock copolymers composed of sulfopropyl ether-modified α-cyclodextrins (α-CDs) threaded onto a poly(ethylene glycol) (PEG) chain as a PRX segment and
Mengya Cao et al.
Macromolecular rapid communications, 40(20), e1900296-e1900296 (2019-08-15)
The poly[oligo(ethylene oxide) methyl ether methacrylate]s, POEOMA24 and POEOMA78 with average degree of polymerization (DP) of 24 and 78, respectively, are separately achieved by initiators for continuous activator regeneration (ICAR) atom transfer radical polymerization (ATRP) of OEOMA300 monomer. The mixtures
Olesya Daikos et al.
Physical chemistry chemical physics : PCCP, 18(47), 32369-32377 (2016-11-18)
Pentabrominated and fluorinated aromatic (meth)acrylates as well as their non-halogenated counterparts have been studied with the aim to avoid conventional photoinitiators and to overcome some negative consequences related to their use. Therefore, RTIR spectroscopy, laser flash photolysis and GC/MS were

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