Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

363685

Sigma-Aldrich

Silver carbonate on Celite®

extent of labeling: ~50 wt. % loading

Synonym(s):

Fetizon′s reagent

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
Ag2CO3
CAS Number:
534-16-7
Molecular Weight:
275.75
EC Number:
208-590-3
MDL number:
MFCD00003403
UNSPSC Code:
12352302
PubChem Substance ID:
24862209
NACRES:
NA.23
form:
powder and chunks
Pricing and availability is not currently available.

form

powder and chunks

Quality Level

100

concentration

45-60 wt. % (by KSCN, titration)

extent of labeling

~50 wt. % loading

SMILES string

[Ag]OC(=O)O[Ag]

InChI

1S/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

KQTXIZHBFFWWFW-UHFFFAOYSA-L

Application

Employed in the silver ion induced preparation of α-keto acetals and α,α-dialkoxy imines.[1] Catalyzes the generation of stereospecific unsaturated aldehydes from vinylic halides and primary amines.[2]

Legal Information

Celite is a registered trademark of Imerys Minerals California, Inc.

Pictograms

CorrosionEnvironment
GHS05,GHS09

Signal Word

Danger

Hazard Statements

H318,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
SHBL5135
SHBL2556
SHBL1869
SHBL1873
SHBK4656

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Synthesis, 427-427 (1994)
Tetrahedron Letters, 31, 6641-6641 (1990)
Sukalyan Bhadra et al.
Journal of the American Chemical Society, 134(24), 9938-9941 (2012-06-12)
Decarboxylative Chan-Evans-Lam-type couplings are presented as a new strategy for the regiospecific construction of diaryl and alkyl aryl ethers starting from easily available aromatic carboxylic acids. They allow converting various aromatic carboxylate salts into the corresponding aryl ethers by reaction
B Pérez-Uz et al.
The Journal of eukaryotic microbiology, 48(3), 338-347 (2001-06-20)
A new genus and species combination are proposed for Urocryptum tortum n. gen., n. comb., a scuticociliate with a polymorphic life cycle. This marine ciliate was isolated from a sample taken at Gokasho Bay in Mie Prefecture (Japan). Specimens from
Satish Malik et al.
Carbohydrate research, 345(5), 559-564 (2010-02-05)
A simple, mild, and regioselective method has been developed for the selective benzylation and p-methoxybenzylation of carbohydrate derivatives in high yields using Ag(2)CO(3) as the promoter. Benzylation of base-labile substrates, for which other reported methods are of little use, has
View All Related Papers

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service