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359009

Sigma-Aldrich

Cerium(IV) sulfate

Synonym(s):

Ceric sulfate, Cerium disulfate

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About This Item

Linear Formula:
Ce(SO4)2
CAS Number:
13590-82-4
Molecular Weight:
332.24
EC Number:
237-029-5
MDL number:
MFCD00148852
UNSPSC Code:
12161600
PubChem Substance ID:
24862046
NACRES:
NA.22

form

powder

Quality Level

100

reaction suitability

core: cerium
reagent type: catalyst

density

3.01 g/mL at 25 °C (lit.)

SMILES string

[Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O

InChI

1S/Ce.2H2O4S/c;2*1-5(2,3)4/h;2*(H2,1,2,3,4)/q+4;;/p-4

InChI key

VZDYWEUILIUIDF-UHFFFAOYSA-J

Application

Cerium(IV) sulfate can be used to catalyze:
  • Selective oxidation of secondary alcohols to the corresponding ketones using sodium bromate as the oxidant.
  • Direct sulfonation of methane with sulfur trioxide to methanesulfonic acid in sulfuric acid.
  • Synthesis of 14-aryl- or 14-alkyl-14H-dibenzo[aj]xanthenes from the condensation of 2-naphthol and aldehydes under solvent-free and microwave conditions.

Reactant for:
  • Preparation of spherical-like nanoparticles CeO2 nanoparticles for NO reductions reactions

  • Oxidizing agent

Other Notes

may contain excess sulfate

Pictograms

CorrosionEnvironment
GHS05,GHS09

Signal Word

Danger

Hazard Statements

H314,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Amadou Dawé et al.
Zeitschrift fur Naturforschung. C, Journal of biosciences, 73(5-6), 211-219 (2018-02-17)
Despite the well-documented benefits of Combretum fragrans in Cameroon, only few scientific works have been done on it. In this study we isolated eight compounds from the leaves extract of C. fragrans: velutin (1), belamcanidin (2), cirsilineol (3), cirsimaritin (4)
S M Sultan et al.
Journal of pharmaceutical and biomedical analysis, 7(3), 279-286 (1989-01-01)
A simple and accurate kinetic method for the determination of propranolol has been developed. Cerium(IV) sulphate (0.5 M) is used to oxidize propranolol in 2 M sulphuric acid at room temperature to the ketone form that absorbs light at a
Hidayat Hussain et al.
Chemistry & biodiversity, 12(2), 289-294 (2015-02-14)
A new polychlorinated triphenyl diether named microsphaerol (1), has been isolated from the endophtic fungus Microsphaeropsis sp. An intensive phytochemical investigation of the endophytic fungus Seimatosporium sp., led to the isolation of a new naphthalene derivative named seimatorone (2) and
J Bello-Martínez et al.
Pharmacognosy magazine, 13(Suppl 2), S289-S293 (2017-08-16)
The aim of this study was to isolate the compounds responsible for antiproliferative activity of A bioassay-guided fractionation of ethanol extract of The flavonoid brazilin (1) was isolated from the heartwood of Brazilin: (6a The flavonoid brazilin was isolated from
Ju Peng Wang et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71(1), 204-208 (2008-02-05)
A simple, sensitive and rapid flow-injection chemiluminescence method has been developed for the determination of ferulic acid based on the chemiluminescence reaction of ferulic acid with rhodamine 6G and ceric sulfate in sulphuric acid medium. Strong chemiluminescence signal was observed
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