242969

Sodium diphenylamine-4-sulfonate

ACS reagent

• Synonym(s): 4-(Phenylamino)benzenesulfonic acid sodium salt, Diphenylamine-4-sulfonic acid sodium salt
• Empirical Formula (Hill Notation): C₁₂H₁₀NNaO₃S
• CAS Number: 6152-67-6
• Molecular Weight: 271.27
• EC Number: 228-165-6
• MDL number: MFCD00036468
• UNSPSC Code: 12352100
• PubChem Substance ID: 24854595
• NACRES: NA.21

Properties

• grade: ACS reagent
• Quality Level: 200
• technique(s): titration: suitable
• SMILES string: [Na+].[O-]S(=O)(=O)c1ccc(Nc2ccccc2)cc1
• InChI: 1S/C12H11NO3S.Na/c14-17(15,16)12-8-6-11(7-9-12)13-10-4-2-1-3-5-10;/h1-9,13H,(H,14,15,16);/q;+1/p-1
• InChI key: DGXTZMPQSMIFEC-UHFFFAOYSA-M

Description

General description

Sodium diphenylamine-4-sulfonate has the ability to form colored complexes with metal ions. Hence it is commonly used as an indicator to estimate the concentration of metal ions. It is also an efficient quencher of electrochemiluminescence of tris (2, 2′-bipyridine)-ruthenium (II).

Application

Sodium diphenylamine-4-sulfonate may be used in the synthesis of poly-(aniline-co-N-(4-sulfophenyl)aniline via polymerization with aniline. It may also be used as a reductant in the synthesis of branched gold nanocrystals from gold(III) chloride trihydrate in the presence of polyethylene glycol. These nanocrystals have potential application as electrocatalysts.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves