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806455

Sigma-Aldrich

2,6-Dimethoxyanilino(oxo)acetic acid

Synonym(s):

[(2,6-Dimethoxyphenyl)amino](oxo)acetic acid, [(2,6-Dimethoxyphenyl)carbamoyl]formic acid

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About This Item

Empirical Formula (Hill Notation):
C10H11NO5
CAS Number:
2097273-59-9
Molecular Weight:
225.20
UNSPSC Code:
12352300
PubChem Substance ID:
329769012
NACRES:
NA.22

form

powder

Quality Level

100

reaction suitability

reagent type: ligand

SMILES string

O=C(C(O)=O)NC1=C(OC)C=CC=C1OC

InChI

1S/C10H11NO5/c1-15-6-4-3-5-7(16-2)8(6)11-9(12)10(13)14/h3-5H,1-2H3,(H,11,12)(H,13,14)

InChI key

AULRRTNGXKPSPX-UHFFFAOYSA-N

General description

2,6-Dimethoxyanilino(oxo)acetic acid is also referred to as [(2,6-dimethylphenyl)carbamoyl]formic acid.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302

Precautionary Statements

P264 - P270 - P301 + P312 - P501

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
0000363970
0000363970
0000222193
0000268016
0000202879

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Yu Zhang et al.
Organic letters, 14(12), 3056-3059 (2012-06-06)
DMPAO has been found to be a powerful ligand to enable copper-catalyzed coupling of aryl halides with aliphatic acyclic secondary amines take place under relatively mild conditions, and coupling of aryl halides with primary amines and cyclic secondary amines proceeds

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