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Sigma-Aldrich

F8BT

average Mn ≤25000

Synonym(s):

Poly(9,9-dioctylfluorene-alt-benzothiadiazole), Poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)]

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About This Item

Linear Formula:
(C35H42N2S)n
CAS Number:
210347-52-7
UNSPSC Code:
12352103
NACRES:
NA.23

form

powder

Quality Level

100

mol wt

average Mn ≤25000

solubility

THF: soluble
chloroform: soluble

fluorescence

λex 447 nm; λem 530-560 nm in chloroform

Mw/Mn

<3

semiconductor properties

P-type (mobility=4×10−3 cm2/V·s)

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General description

F8BT is a fluorene copolymer that is used as a light-emitting polymer (LEP) with low energy of lowest unoccupied molecular orbital (LUMO), high electron mobility and luminance.

Application

F8BT can be used with poly(9,9-di-n-octylfluorenyl-2,7-diyl) (PTO) to map the effect of noise sources on photoconducting charge transports by evaluating the conductivity and noise source density (Nt). It may also form a nanocomposite with single walled carbon nanotube (SWCNT) with excellent electric properties and high Seebeck coefficient, for potential application in the development of photovoltaic power and biomass energy. Organic light emitting diode (OLED) devices can be fabricated by depositing a blend of F8 and F8BT on PEDOT:PSS films.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF4753V
MKCQ9539
MKCR7791
MKCL7808
MKCG7492

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Morphology-dependent trap formation in bulk heterojunction photodiodes
Shao G, et al.
The Journal of Physical Chemistry B, 117(16), 4654-4660 (2013)
Surface, interface and electronic properties of F8: F8BT polymeric thin films used for organic light-emitting diode applications
Borges BG, et al.
Polymer International, 67(6), 691-699 (2018)
Efficient polymer light-emitting diode using air-stable metal oxides as electrodes
Bolink HJ, et al.
Advanced Materials, 21(1), 79-82 (2009)
Enhanced figure of merit of poly (9, 9-di-n-octylfluorene-alt-benzothiadiazole) and SWCNT thermoelectric composites by doping with FeCl3
Zhou X, et al.
Journal of Applied Polymer Science, 16(3), 47011-47011 (2018)
Lay-Lay Chua et al.
Nature, 434(7030), 194-199 (2005-03-11)
Organic semiconductors have been the subject of active research for over a decade now, with applications emerging in light-emitting displays and printable electronic circuits. One characteristic feature of these materials is the strong trapping of electrons but not holes: organic
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