656631
1,3-Bis(2,4,6-trimethylphenyl)imidazolinium chloride
95%
Synonym(s):
1,3-Dimesitylimidazolidinium chloride, 4,5-Dihydro-1,3-bis(2,4,6-trimethylphenyl)-1H-imidazolium chloride, 4,5-Dihydro-1,3-dimesityl-1H-imidazolium chloride, N,N′-(2,4,6-Trimethylphenyl)dihydroimidazolium chloride
About This Item
Recommended Products
Quality Level
Assay
95%
reaction suitability
reagent type: ligand
mp
280-286 °C
SMILES string
[Cl-].Cc1cc(C)c(N2CC[N+](=C2)c3c(C)cc(C)cc3C)c(C)c1
InChI
1S/C21H27N2.ClH/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;/h9-13H,7-8H2,1-6H3;1H/q+1;/p-1
InChI key
COGMCBFILULEOS-UHFFFAOYSA-M
Related Categories
General description
Application
Precursor to an N-heterocyclic carbene catalysts used for:
- A regioselective cycloadditon of terminal acetylenes with azides leading to 1,4-disubstitutedtriazoles. Internal acetylenes can also be used with this catalyst.
- Markovnikov-type hydration of terminal alkynes
- Hydrosilylation of ketones and cycloaddition of azides and alkynes
- Suzuki-Miyaura reactions
- Luminescence experiments
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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