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429058

Sigma-Aldrich

2-Fluoroethylamine hydrochloride

technical grade, 90%

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About This Item

Linear Formula:
FCH2CH2NH2 · HCl
CAS Number:
460-08-2
Molecular Weight:
99.54
EC Number:
207-302-3
MDL number:
MFCD00008161
UNSPSC Code:
12352100
PubChem Substance ID:
24866832
NACRES:
NA.22
Pricing and availability is not currently available.

grade

technical grade

Quality Level

100

Assay

90%

form

solid

mp

99-103 °C (lit.)

functional group

amine
fluoro

SMILES string

Cl.NCCF

InChI

1S/C2H6FN.ClH/c3-1-2-4;/h1-2,4H2;1H

InChI key

YRRZGBOZBIVMJT-UHFFFAOYSA-N

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General description

2-Fluoroethylamine hydrochloride is a fluorinated alkylammonium salt. Studies suggest that adding a fluorine atom to it leads to double gauche effect in the resulting 2,2-difluoroethylamine chloride.[1] Microwave spectral studies for 2-fluoroethylamine has been conducted.[2]

Application

2-Fluoroethylamine hydrochloride may be used in the synthesis of the following:
  • 2-fluoroethylisocyanate[3]
  • 1,3-bis-(2-fluoroethyl) urea (BFU)[3]
  • N-2-fluoroethylmaleimide[4]
  • [Cu4(O)(Ln)2(CH3COO)4] where HL= 4-methyl-2,6-bis(2-fluoroethyliminomethyl) phenol[5]
  • 1-O-(4-(2-fluoroethyl-carbamoyloxymethyl)-2-nitrophenyl)-O-β-D-glucopyronuronate (FEAnGA)[6]

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
SHBL0278
SHBK9619
SHBJ9776
SHBF9757V
SHBB0816V

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Development of a new thiol site-specific prosthetic group and its conjugation with [Cys40]-exendin-4 for in vivo targeting of insulinomas.
Yue X, et al.
Bioconjugate Chemistry, 24(7), 1191-1200 (2013)
Conformational analysis of 2, 2-difluoroethylamine hydrochloride: double gauche effect.
Silla JM, et al.
Beilstein Journal of Organic Chemistry, 10(1), 877-882 (2014)
Tetranuclear copper (II)-Schiff-base complexes as active catalysts for oxidation of cyclohexane and toluene.
Roy P and Manassero M.
Dalton Transactions, 39(6), 1539-1545 (2010)
Microwave-spectrum, conformational equilibrium, intramolecular hydrogen-bonding, dipole-moments, N-14 nuclear-quadrupole coupling-constants and centrifugal-distortion constants of 2-fluoroethylamine.
Marstokk KM and Mollendal H.
Acta Chemica Scandinavica, 34(1), 15-29 (1980)
Synthesis of 18F-labelled 2-fluoroethyl-nitrosoureas.
Farrokhzad S, et al.
Canadian Journal of Chemistry, 62(11), 2107-2112 (1984)
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