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409022

Sigma-Aldrich

Poly(diallyldimethylammonium chloride) solution

average Mw 200,000-350,000 (medium molecular weight), 20 wt. % in H2O

Synonym(s):

PDADMAC

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About This Item

Linear Formula:
(C8H16ClN)n
CAS Number:
26062-79-3
MDL number:
MFCD00192409
UNSPSC Code:
12162002
NACRES:
NA.23

form

viscous liquid

Quality Level

100

mol wt

average Mw 200,000-350,000 (medium molecular weight)

concentration

20 wt. % in H2O

refractive index

n20/D 1.375

viscosity

250-500 cP(25 °C, Brookfield)

density

1.04 g/mL at 25 °C

InChI

1S/C8H16N.ClH/c1-5-7-9(3,4)8-6-2;/h5-6H,1-2,7-8H2,3-4H3;1H/q+1;/p-1

InChI key

GQOKIYDTHHZSCJ-UHFFFAOYSA-M

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General description

Poly(diallyldimethylammonium chloride) solution (PDADMAC) is a cationic polyelectrolyte prepared by the radical polymerization of diallyldimethylammonium chloride (DADMAC) in presence of a catalyst in the form of an organic peroxide. It is widely utilized as a flocculant.

Application

PDADMAC can be used as an electrolytic solution in a variety of applications such as drug delivery, biomedical systems, and sensors, which include biosensors and chemical sensors.

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW4667
MKCV4543
MKCT4103
MKCQ9161
MKCS0272

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Synthesis and use of PolyDADMAC for water purification
Biennial Conference of the Water Institute of Southern Africa, Durban, South Africa, 46(8), 2584-2594 (2002)
Polyelectrolyte multilayer as matrix for electrochemical deposition of gold clusters: toward super-hydrophobic surface
Zhang X, et al.
Journal of the American Chemical Society, 126(10), 3064-3065 (2004)
Synthesis and solution properties of poly (N-isopropylacrylamide-co-diallyldimethylammonium chloride)
Deng Y and Pelton R
Macromolecules, 28(13), 4617-4621 (1995)
Urszula Bazylińska et al.
European journal of pharmaceutical sciences : official journal of the European Federation for Pharmaceutical Sciences, 47(2), 406-420 (2012-07-17)
There is great clinical interest in developing novel nanocarriers for hydrophobic cyanine dyes used as photosensitizing agents in photodynamic therapy (PDT). In the present study we have employed nanoemulsion-templated oil-core multilayer nanocapsules as robust nanocarriers for a cyanine-type photosensitizer IR-786.
John Crosby et al.
Chemical communications (Cambridge, England), 48(97), 11832-11834 (2012-10-27)
Compartmentalization of the minimal complex of actinorhodin polyketide synthase in coacervate liquid droplets produces enhanced yields of shunt polyketides under conditions of low and high ionic strength.
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Articles

Polyelectrolyte Multilayer Films and Membrane Functionalization

We present an article that discusses two applications in particular; first, using these layers as polyelectrolyte membranes to control permeability.

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