379387
Dithiooxamide
97%
Synonym(s):
Dithiooxalic diamide, Rubeanic acid
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About This Item
Linear Formula:
NH2CSCSNH2
CAS Number:
Molecular Weight:
120.20
Beilstein:
605577
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
form
powder
mp
≥300 °C (lit.)
solubility
ethanol: soluble 40 mg/10 mL, clear, red
functional group
amine
SMILES string
NC(=S)C(N)=S
InChI
1S/C2H4N2S2/c3-1(5)2(4)6/h(H2,3,5)(H2,4,6)
InChI key
OAEGRYMCJYIXQT-UHFFFAOYSA-N
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General description
Dithiooxamide is reported to form complexes with Ni(II).
Application
Dithiooxamide may be used in the following studies:
- Synthesis of thiazolothiazole-linked porous organic polymers under solvothermal conditions.
- As modifier to prepare the modified glassy carbon electrode, used to investigate the electrochemical properties of quercetin, an important flavonoid derivative.
- Synthesis of new chelating resin of dithiooxamide (rubeanic acid)-formaldehyde (DTOF), used in separation and concentration of silver ions.
- Synthesis of N,N′-disubstituted dithiooxamides.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Nickel (II) complexes with dithiooxamide, N, N'-di-methyl-and N, N'-di-hydroxyethyl-dithiooxamide.
Peyronel G, et al.
Inorgorganica Chimica Acta, 5, 627-633 (1971)
Preparation of Dithiooxamide Derivatives.
Hurd RN, et al.
The Journal of Organic Chemistry, 26(10), 3980-3987 (1961)
Xiang Zhu et al.
Chemical communications (Cambridge, England), 50(95), 15055-15058 (2014-10-21)
Thiazolothiazole-linked porous organic polymers have been synthesized from a facile catalyst-free condensation reaction between aldehydes and dithiooxamide under solvothermal conditions. The resultant porous frameworks exhibit a highly selective uptake of CO2 over N2 under ambient conditions.
E Guibal et al.
International journal of biological macromolecules, 28(5), 401-408 (2001-04-28)
Glutaraldehyde-cross-linked chitosan (GCC), thiourea derivative of chitosan (TGC) and rubeanic acid derivative of chitosan (RADC) have previously been shown to be very efficient at removing platinum and palladium from single component dilute acidic solutions. This study examines the competitive sorption
Yurii A Simonov et al.
Organic & biomolecular chemistry, 1(16), 2922-2929 (2003-09-13)
The hydrogen-bonding networks for seven new binary compounds of dithiooxamide, (NH2CS)2 (dtox) and dithiobiurea (NH2CSNH)2 (dtur) with crown ethers, 18-crown-6 (18C6), 15-crown-5 (15C5), 12-crown-4 (12C4), cis-syn-cis-(DCHA), and cis-anti-cis-(DCHB) isomers of dicyclohexyl-18 -crown-6 are discussed. (15C5.dtox), (18C6.dtur) and (DCHB.dtur) afford one-dimensional
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