237523
Palladium on barium carbonate
reduced, extent of labeling: 5 wt. % loading
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About This Item
Linear Formula:
Pd
MDL number:
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.23
Recommended Products
Quality Level
form
solid
reaction suitability
reagent type: catalyst
core: palladium
greener alternative product characteristics
Design for Energy Efficiency
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sustainability
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extent of labeling
5 wt. % loading
greener alternative category
SMILES string
[Pd++].[Ba++].[O-]C([O-])=O.[O-]C([O-])=O
InChI
1S/2CH2O3.Ba.Pd/c2*2-1(3)4;;/h2*(H2,2,3,4);;/q;;2*+2/p-4
InChI key
NFXIBAPFNPIUGD-UHFFFAOYSA-J
Application
Palladium on barium carbonate (5% Pd/BaCO3) is a palladium catalyst that can be used in the cross-coupling reaction of arenediazonium salts with boronic acid at low catalytic loading. It can also be used as a catalyst in the diastereoselective hydrogenations of the imine for the synthesis of chiral trifluoromethyl benzylamines.
Other Notes
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Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Efficient and Practical Cross-Coupling of Arenediazonium Tetrafluoroborate Salts with Boronic Acids Catalyzed by Palladium (0)/Barium Carbonate
Felpin F and Fouquet E
advanced synthesis and catalysis, 350(6), 863-868 (2008)
Efficient and Practical Cross-Coupling of Arenediazonium Tetrafluoroborate Salts with Boronic Acids Catalyzed by Palladium (0)/Barium Carbonate
Felpin F and Fouquet E
Advanced Synthesis & Catalysis, 350(6), 863-868 (2008)
Synthesis of Chiral Trifluoromethyl Benzylamines by Heterogeneous Catalytic Reductive Amination
Dasgupta S, et al.
Topics in Catalysis, 59(13-14), 1207-1213 (2016)
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