234982
Allyl(chloro)dimethylsilane
97%
Synonym(s):
ADMCS, Allyldimethylchlorosilane
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About This Item
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Quality Level
Assay
97%
form
liquid
refractive index
n20/D 1.427 (lit.)
bp
111-113 °C (lit.)
density
0.891 g/mL at 25 °C (lit.)
SMILES string
C[Si](C)(Cl)CC=C
InChI
1S/C5H11ClSi/c1-4-5-7(2,3)6/h4H,1,5H2,2-3H3
InChI key
KMVZWUQHMJAWSY-UHFFFAOYSA-N
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Application
Allyl(chloro)dimethylsilane has been used in:
- the synthesis of cyclo-1,1′,4,4′-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene
- silylation of silicic acid
- the preparation of phenylenebis(silanediyl triflates), useful synthons for organosilicon polymers
- O-silylation of phenyl sulfones
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Liq. 2 - Skin Corr. 1B
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point(F)
42.8 °F - closed cup
Flash Point(C)
6 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Structure of cyclo-1, 1′, 4, 4′-bis (1, 1, 3, 3-tetramethyl-1,3-disiloxanediyl) dibenzene.
Acta Crystallographica Section C, Crystal Structure Communications, 49(10), 1845-1848 (1993)
Oligo-and polysiloxanes.
Progress in Polymer Science, 29(3), 149-182 (2004)
Helvetica Chimica Acta, 77, 972-972 (1994)
Journal of the American Chemical Society, 116, 5657-5657 (1994)
Polymers, 12(5) (2020-05-10)
The scientific reports on polyhedral oligomeric silsesquioxanes are mostly focused on the formation of completely condensed T8 cubic type structures and recently so-called double-decker derivatives. Herein, we report on efficient synthetic routes leading to trifunctionalized, open-cage silsesquioxanes with alkenyl groups
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