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234834

Sigma-Aldrich

Cyclopentadienyltitanium(IV) trichloride

97%

Synonym(s):

CpTiCl3

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About This Item

Empirical Formula (Hill Notation):
C5H5Cl3Ti
CAS Number:
1270-98-0
Molecular Weight:
219.32
MDL number:
MFCD00003724
UNSPSC Code:
12161600
PubChem Substance ID:
24854059
NACRES:
NA.22

Quality Level

100

Assay

97%

form

solid

reaction suitability

core: titanium
reagent type: catalyst

mp

210 °C (dec.) (lit.)

SMILES string

Cl[Ti](Cl)Cl.[CH]1[CH][CH][CH][CH]1

InChI

1S/C5H5.3ClH.Ti/c1-2-4-5-3-1;;;;/h1-5H;3*1H;/q;;;;+3/p-3

InChI key

AENCLWKVWIIOQH-UHFFFAOYSA-K

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Application

Precusor for cyclopentadienyltitanium(IV) complexes, and used as catalysts for alkene polymerizations

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000238411
0000238418
0000223865
0000229634
MKBQ0353V

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McGrane, P. L.; Jensen, M. et al.
Journal of the American Chemical Society, 114, 5459-5459 (1992)
David Hermann Lamparelli et al.
Polymers, 11(4) (2019-04-19)
The direct synthesis of syndiotactic polystyrene-block-polyethylene copolymer (sPS-b-PE) with a diblock structure has been achieved. The synthetic strategy consists of the sequential stereocontrolled polymerization of styrene and ethylene in the presence of a single catalytic system: cyclopentadienyltitanium(IV) trichloride activated by
Erker, G.; Aulbach, M. et al.
Journal of the American Chemical Society, 115, 4590-4590 (1993)
Ricci, G.; Italia, S. et al.
The Journal of Organic Chemistry, 451, 67-67 (1993)
Komal Sethi et al.
Journal of colloid and interface science, 456, 59-65 (2015-06-21)
In this paper, we report the synthesis, characterization of drug-doped organically modified titania nanoparticles, and their applications in sustained drug release. The drug-doped nanoparticles were synthesized in the hydrophobic core of oil-in-water microemulsion medium. Structural aspects obtained through TEM and

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