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208981

Sigma-Aldrich

Potassium hexachloroiridate(IV)

technical grade

Synonym(s):

Iridium potassium chloride

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About This Item

Linear Formula:
K2IrCl6
CAS Number:
16920-56-2
Molecular Weight:
483.13
EC Number:
240-976-7
MDL number:
MFCD00011369
UNSPSC Code:
12352302
PubChem Substance ID:
24852223
NACRES:
NA.23

grade

technical grade

Quality Level

100

form

powder

concentration

≥39.0% Ir (gravimetric)

mp

>385 °C (lit.)

SMILES string

[K+].[K+].Cl[Ir--](Cl)(Cl)(Cl)(Cl)Cl

InChI

1S/6ClH.Ir.2K/h6*1H;;;/q;;;;;;+4;2*+1/p-6

InChI key

WEKZJZDULNNSCD-UHFFFAOYSA-H

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Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW6421
MKCV8397
MKCV5691
MKCT4599
MKCR9192

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V Duarte et al.
Nucleic acids research, 27(2), 496-502 (1998-12-24)
Oxidative damage to DNA bases commonly resultsin the formation of oxidized purines, particularly 7,8-dihydro-8-oxoguanine (8-oxoG) and 7,8-dihydro-8-oxoadenine (8-oxoA), the former being a well-known mutagenic lesion. Since 8-oxoG is readily subject to further oxidation compared with normal bases, the insertion of
G M Kolodny et al.
Cancer research, 43(7), 3101-3103 (1983-07-01)
Sodium hexachloroiridate injected 1 day after i.p. injection of 10(6) mouse ovarian tumor cells prevents the appearance of ascitic tumors in mice. Mice given injections of tumor cells all die at 20 to 30 days after tumor injection. Mice treated
Nootan Bhattarai et al.
Inorganic chemistry, 51(24), 13303-13311 (2012-11-29)
The aqueous oxidations of glutathione (GSH) by [IrCl(6)](2-), [Fe(bpy)(2)(CN)(2)](+), and [Fe(bpy)(CN)(4)](-) are described. All three reactions are highly susceptible to catalysis by traces of copper ions, but this catalysis can be fully suppressed with suitable chelating agents. The direct oxidation
Salah Boussaad et al.
Journal of the American Chemical Society, 130(12), 3780-3787 (2008-03-07)
In an effort to develop sensitive nanoscale devices for chemical and biological sensing, we have examined, using liquid gating, the conductance of semiconducting single-walled carbon nanotube-based field-effect transistors (SWCNT-FETs) in the presence of redox mediators. As examples, redox couples K3Fe(CN)6/K4Fe(CN)6
Edward P Randviir et al.
Nanoscale, 4(20), 6470-6480 (2012-09-11)
A newly synthesised type of graphene, Q-Graphene, has been physically and electrochemically characterised with Scanning and Transmission Electron Microscopy (SEM, TEM), X-ray Photoelectron Spectroscopy (XPS) and Cyclic Voltammetry (CV). Interpretation of SEM, TEM and XPS data reveal the material to
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