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203653

Sigma-Aldrich

Lithium sulfate

greener alternative

≥99.99% trace metals basis

Synonym(s):

Dilithium sulfate, Lithiophor

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About This Item

Linear Formula:
Li2SO4
CAS Number:
Molecular Weight:
109.94
EC Number:
MDL number:
UNSPSC Code:
12352302
eCl@ss:
38030404
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

≥99.99% trace metals basis

form

solid

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Design for Energy Efficiency
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sustainability

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impurities

≤100.0 ppm Trace Metal Analysis

mp

845 °C (lit.)

density

2.22 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

greener alternative category

SMILES string

[Li+].[Li+].[O-]S([O-])(=O)=O

InChI

1S/2Li.H2O4S/c;;1-5(2,3)4/h;;(H2,1,2,3,4)/q2*+1;/p-2

InChI key

INHCSSUBVCNVSK-UHFFFAOYSA-L

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

Application

Lithium sulfate can be used:
  • In the pretreatment of graphite electrodes of lithium-ion batteries(LIBs). LiSO4-treated electrodes show excellent cycling performance and low interfacial impedance resulting in faster charging of LIBs.
  • As a precursor to synthesize sheet-like Li2S@C nanocomposites which are cathode materials for LIBs.
  • As an electrolyte for intermediate temperature fuel cells.
  • As a processing additive to protect Ni-rich layered oxide cathodes, resulting in improved electrochemical performance.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Structure and ionic conductivity of lithium sulphate-aluminum oxide ceramics
B. Zhu, et al.},
Solid State Ionics, 70-71, 125-129 (1994)
Pretreatment of Graphite Anodes with Lithium Sulfate to Improve the Cycle Performance of Lithium-Ion Batteries
Xiaoling Cui, et al.
Energy Technology, 5, 549-556 (2017)
A high energy density Li2S@ C nanocomposite cathode with a nitrogen-doped carbon nanotube top current collector
Su Zhang, et al.
Journal of Material Chemistry A, 3, 18913-18919 (2015)
Janaína Teles de Faria et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 877(27), 3031-3037 (2009-09-01)
Xylose reductase (XR) from Debaryomyces hansenii was extracted by partitioning in aqueous two-phase systems (ATPS) composed of polyethylene glycol (PEG) 4000 in the presence of different salts, specifically sodium sulfate, lithium sulfate and potassium phosphate. Batch extractions were carried out
Guido Straten et al.
Current Alzheimer research, 8(8), 853-859 (2011-08-31)
Preclinical and clinical studies gave evidence that lithium could be useful in the treatment of Alzheimer's disease (AD). One possible mechanism of action might be the induction of neurotrophins. Recently, we found a significant increase of brain-derived neurotrophic factor (BDNF)

Articles

Lithium-ion batteries' characteristics make them popular for electricity storage due to portability, rechargeability, and low cost.

Lithium-ion batteries' characteristics make them popular for electricity storage due to portability, rechargeability, and low cost.

Lithium-ion batteries' characteristics make them popular for electricity storage due to portability, rechargeability, and low cost.

Lithium-ion batteries' characteristics make them popular for electricity storage due to portability, rechargeability, and low cost.

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