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143677

Sigma-Aldrich

2-(Bromomethyl)naphthalene

96%

Synonym(s):

β-(Bromomethyl)naphthalene, β-Naphthylmethyl bromide, (Naphthalen-2-yl)methyl bromide, 2-(Bromomethyl)naphthalene, 2-Menaphthyl bromide, 2-Naphthylmethyl bromide

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About This Item

Linear Formula:
C10H7CH2Br
CAS Number:
939-26-4
Molecular Weight:
221.09
Beilstein:
636546
EC Number:
213-359-5
MDL number:
MFCD00004123
UNSPSC Code:
12352100
PubChem Substance ID:
24848601
NACRES:
NA.22

Quality Level

100

Assay

96%

bp

213 °C/100 mmHg (lit.)

mp

51-54 °C (lit.)

functional group

bromo

storage temp.

2-8°C

SMILES string

BrCc1ccc2ccccc2c1

InChI

1S/C11H9Br/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-7H,8H2

InChI key

RUHJZSZTSCSTCC-UHFFFAOYSA-N

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Application

2-(Bromomethyl)naphthalene (2-BMN) can be employed as a starting material in the synthesis of 2-(fluoromethyl)naphthalene , 2-naphthylmethyl azide , 2-naphthalenecarboxaldehyde , diselenide, bis(2-naphthalenylmethyl) , 1H-1,2,3-triazole, 4,4′-(1,4-phenylene)bis[1-(2-naphthalenylmethyl).

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H314,H317

Hazard Classifications

Skin Corr. 1B - Skin Sens. 1

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

110 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBJ7258
STBJ6043
STBH2765
STBG0636V
STBC9168V

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A novel and efficient method for the synthesis of dibenzyl diselenides
Tian F and Lu S
J. Chem. Res. (M), 2004(9), 632-633 (2004)
Probing the reactivity of o-phthalaldehydic acid/methyl ester: synthesis of N-isoindolinones and 3-arylaminophthalides
Mamidyala SK and Cooper MA
Chemical Communications (Cambridge, England), 49(75), 8407-8409 (2013)
Silica-based magnetic manganese nanocatalyst-applications in the oxidation of organic halides and alcohols
Sharma RK, et al.
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Dimeric and trimeric triazole based molecules as a new class of Hsp90 molecular chaperone inhibitors
Terracciano S, et al.
European Journal of Medicinal Chemistry, 65(9), 464-476 (2013)
Kuppuswamy Arumugam et al.
Inorganic chemistry, 46(8), 3283-3288 (2007-03-16)
The reaction of P4S10 with acyloins, RC(O)CH(OH)R, in refluxing dioxane, followed by the addition of alkylating agents, forms dithiolene thiophosphoryl thiolate compounds, (R2C2S2)P(S)(SR'), which are readily isolated and purified. The compounds that have been prepared and identified spectroscopically are those
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