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793620

Sigma-Aldrich

Lithium chloride

anhydrous, free-flowing, Redi-Dri™, ReagentPlus®, 99%

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About This Item

Linear Formula:
LiCl
CAS Number:
7447-41-8
Molecular Weight:
42.39
EC Number:
231-212-3
MDL number:
MFCD00011078
UNSPSC Code:
12352302
PubChem Substance ID:
329768091
NACRES:
NA.21

grade

anhydrous

Quality Level

100

product line

ReagentPlus®
Redi-Dri™

Assay

99%

form

powder or crystals

quality

free-flowing

pH

6

mp

605 °C (lit.)

SMILES string

[Li+].[Cl-]

InChI

1S/ClH.Li/h1H;/q;+1/p-1

InChI key

KWGKDLIKAYFUFQ-UHFFFAOYSA-M

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General description

Redi-Dri™ technology eliminates clumping and the need for complicated procedures to keep your salts free-flowing. Keeping your salts dry helps improve your results by giving accurate measurements and easier-to-handle salts and buffers. Rather than drying your salts in an oven or desiccator or breaking them apart manually, Redi-Dri™ ensures that your salts will remain easy-to-use for months without worrying about anti-caking agents. Even after repeated openings you can be assured that your results are always accurate. Redi-Dri™ saves you time, energy and money by keeping your salts usable for longer!

Application

Lithium chloride can be used as a catalyst in the solvent-free:
  • Cyanosilylation of aldehydes and ketones with cyanotrialkylsilanes to give silylated cyanohydrins.
  • Microwave-assisted Claisen-Schmidt condensation to prepare α, β-unsaturated ketones.
It can also be used as:
  • An additive in the Pd-catalyzed Stille coupling of aryl iodides with arylstannanes to synthesize corresponding biphenyls.
  • A catalyst for the chemo- and regioselective demethylation of aryl methyl ethers to corresponding phenol products.

Features and Benefits

  • Increased efficiency – Eliminate time and effort of loosening hardened powders
  • Safety – Avoid risks of using tools of force to break up clumps
  • Economy – Faster preparation and solvation increase productivity and reduce costs
  • Assured quality – Excellent, expert-tested quality with no anti-caking agents
  • Flexible volumes – Available from research amounts to scale-up quantities

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Proceedings of the National Academy of Sciences of the United States of America, 111(40), 14325-14331 (2014-09-17)
Human telomeric DNA consists of tandem repeats of the sequence 5'-TTAGGG-3' that can fold into various G-quadruplexes, including the hybrid, basket, and propeller folds. In this report, we demonstrate use of the α-hemolysin ion channel to analyze these subtle topological
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Neuropsychopharmacology : official publication of the American College of Neuropsychopharmacology, 40(2), 327-337 (2014-07-19)
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Redi-Dri™ prevents hygroscopic powders, such as inorganic salts, from absorbing moisture and forming clumps, leaving the salts free-flowing every time.

Redi-Dri™ – The World of Free-flowing Hygroscopic Products

Redi-Dri™ prevents hygroscopic powders, such as inorganic salts, from absorbing moisture and forming clumps, leaving the salts free-flowing every time.

Redi-Dri™ – The World of Free-flowing Hygroscopic Products

Redi-Dri™ prevents hygroscopic powders, such as inorganic salts, from absorbing moisture and forming clumps, leaving the salts free-flowing every time.

Redi-Dri™ – The World of Free-flowing Hygroscopic Products

Redi-Dri™ prevents hygroscopic powders, such as inorganic salts, from absorbing moisture and forming clumps, leaving the salts free-flowing every time.

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