Journal of molecular modeling, 17(12), 3209-3217 (2011-03-03)
Because of discrepancies in the available experimental data, an extensive theoretical investigation of the formation of the Vilsmeier-Haack (VH) complex has been carried out. The barriers to complex formation calculated using eight different density functional methods (BLYP, B2-PLYP, B3LYP, B3PW91
Phosphorus (P) has only one stable isotope and therefore tracking P dynamics in ecosystems and inferring sources of P loading to water bodies have been difficult. Researchers have recently employed the natural abundance of the ratio of (18)O/(16)O of phosphate
The journal of peptide research : official journal of the American Peptide Society, 65(4), 427-432 (2005-04-09)
A series of homopeptides and their conjugates were synthesized in one pot reaction in the presence of phosphorus oxychloride and the conjugate yield was structurally dependent. Menthol and benzylamine conjugated to the homopeptides quantitatively. Homopeptides when treated with diisopropyloxyphosphite (DIPPH)
Angewandte Chemie (International ed. in English), 51(31), 7688-7691 (2012-06-26)
Three for one: Pyrrolyldipyrromethenes having different functional groups were efficiently synthesized from POCl(3)-promoted condensations between 5-chloro-2-formylpyrrole or isoindole derivatives and suitable pyrrole or indole fragments through a novel nucleophilic aromatic substitution of the initially formed protonated azafulvene rings.
Simple coupling reaction between amino acids and weakly nucleophilic heteroaromatic amines.
Gilles Quéléver et al.
Journal of combinatorial chemistry, 6(5), 695-698 (2004-09-14)
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