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95377

Sigma-Aldrich

Bismuth(III) chloride

purum p.a., ≥97.0% (KT)

Synonym(s):

Bismuth trichloride, Trichlorobismuth

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About This Item

Empirical Formula (Hill Notation):
BiCl3
CAS Number:
7787-60-2
Molecular Weight:
315.34
EC Number:
232-123-2
MDL number:
MFCD00003461
UNSPSC Code:
12352300
PubChem Substance ID:
57653677

grade

purum p.a.

Assay

≥97.0% (KT)

impurities

≤3% water

bp

447 °C (lit.)

mp

230-232 °C (lit.)

anion traces

sulfate (SO42-): ≤500 mg/kg

cation traces

Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Na: ≤200 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES string

Cl[Bi](Cl)Cl

InChI

1S/Bi.3ClH/h;3*1H/q+3;;;/p-3

InChI key

JHXKRIRFYBPWGE-UHFFFAOYSA-K

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Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Bismuth (iii) Chloride Mediated Michaelis-Arbuzov Reaction: A Facile Synthesis of Substituted Arylphosphonates/Phosphinates and Bioactivity Evaluation.
Subramanyam C, et al.
Phosph. Sulfur Relat. Elem. (2015)
Bismuth (III) Chloride-Catalyzed Three-Component Coupling: Synthesis of a-Amino Phosphonates.
Zhan ZP and Li JP.
Synthetic Communications, 35(19), 2501-2508 (2005)
The carbonyl-Diels-Alder reaction catalyzed by bismuth (III) chloride.
Robert H, et al.
Tetrahedron Letters, 39(10), 1161-1164 (1998)
Bismuth (III) Chloride; A Mild and Efficient Catalyst for Synthesis of Thiiranes from Oxiranes.
Mohammadpoor-Baltork I and Aliyan H.
Synthetic Communications, 28(21), 3943-3947 (1998)
Yunqing Zhu et al.
ACS nano, 8(5), 5022-5031 (2014-04-09)
Homopolymers have been considered as a nonideal building block for creating well-defined nanostructures due to their fuzzy boundary between hydrophobic and hydrophilic moieties. However, this unique fuzzy boundary may provide some opportunities for fabricating functional nanomaterials. Presented in this paper

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