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715174

Sigma-Aldrich

Copper(I) 3-methylsalicylate

Synonym(s):

CuMeSal, [2-(Hydroxy-κO)-3-methylbenzoato-κO]copper

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About This Item

Empirical Formula (Hill Notation):
C8H7CuO3
CAS Number:
326477-70-7
Molecular Weight:
214.69
MDL number:
MFCD10699180
UNSPSC Code:
12352300
PubChem Substance ID:
329762948
NACRES:
NA.22

form

solid

reaction suitability

core: copper
reagent type: catalyst

mp

290-292 °C

SMILES string

[Cu+].Cc1cccc(C([O-])=O)c1O

InChI

1S/C8H8O3.Cu/c1-5-3-2-4-6(7(5)9)8(10)11;/h2-4,9H,1H3,(H,10,11);/q;+1/p-1

InChI key

CPPQOSMKJDPRID-UHFFFAOYSA-M

Application

Catalyst for:
  • Carbon-carbon bond formation
  • Oxidative arylthiation
  • Reductive cross-coupling
  • Oxidation reactions
  • Reductive amination

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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