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Journal of nanoscience and nanotechnology, 13(1), 23-32 (2013-05-08)
Semiconducting nanowire heterostructures are of particular interest because of their fascinating properties and potential applications in the field of nanoscale science. CdS, with a direct bandgap of 2.42 eV, is considered to be an excellent material for various optoelectronic applications
Four [(CdSe)13(RNH2)13] derivatives (R = n-propyl, n-pentyl, n-octyl, and oleyl) are prepared by reaction of Cd(OAc)2·2H2O and selenourea in the corresponding primary-amine solvent. Nanoclusters grow in spontaneously formed amine-bilayer templates and are characterized by elemental analysis, IR spectroscopy, UV-vis spectroscopy
Ultrafast time-resolved absorption spectroscopy is used to investigate exciton dynamics in CdSe nanocrystal films. The effects of morphology, quantum-dot versus quantum-rod, and preparation of nanocrystals in a thin film form are investigated. The measurements revealed longer intraband exciton relaxation in
Quantum confinement can dramatically slow down electron-phonon relaxation in nanoclusters. Known as the phonon bottleneck, the effect remains elusive. Using a state-of-the-art time-domain ab initio approach, we model the observed bottleneck in CdSe quantum dots and show that it occurs
The CdS/SiO(2) core/shell nanowires (NWs) with controlled shell thickness were successfully synthesized and subsequently heat-treated at 500 °C. The influences of silica shell coating and annealing processes on their optical properties have been investigated. Compared with original CdS NWs, the
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